dihydrogen peroxide in (C37H78N)3PW4O24; dichloromethane; water

m-CPBA in dichloromethane

1: With tri-isobutyl aluminium; bis-triphenylphosphine-palladium(II) chloride in dichloromethane T=25°C; 12 h; 2: With sodium hydroxide; oxygen in dichloromethane

hydrogen; cyclopentadienyl-rhodium complex in methanol T=25°C; P=30003 Torr; 1 h; Product distribution; Further Variations:Pressures;

Grubb's 2nd generation catalyst in chloroform-d1 T=20°C; 18 h; Inert atmosphere;

1: carbon monoxide With hydrogen; [rhodium(I)(carbonyl)2(acetylacetonate)]; C59H60N4O3P2 in toluene T=100°C; P=7500.75 Torr; 0.5 h; 2: deca-1,9-diene in toluene T=60°C; P=15001.5 Torr; Kinetics;

1: With tri-isobutyl aluminium; bis-triphenylphosphine-palladium(II) chloride in dichloromethane T=25°C; 12 h; 2: With sodium hydroxide; oxygen in dichloromethane

1: With tri-isobutyl aluminium; bis-triphenylphosphine-palladium(II) chloride in dichloromethane T=25°C; 12 h; 2: With sodium hydroxide; oxygen in dichloromethane

9-borabicyclo[3.3.1]nonane dimer; dimethylsulfide borane complex Product distribution;

1.1: 75 percent / AD-mix-β / 2-methyl-propan-2-ol; H2O / 24 h / 0 °C 2.1: 70 percent / collidine / 16 h / 0 - 20 °C 3.1: 99 percent / 2,6-lutidine / CH2Cl2 / 1 h / -78 °C 4.1: 95 percent / NaI; NaHCO3 / acetone / 36 h / Heating 5.1: lithium diisopropylamide / tetrahydrofuran / 0.5 h / cooling 5.2: 50 percent / HMPA / tetrahydrofuran / 16 h / 20 °C 6.1: CH2Cl2 / 20 h / 0 °C 7.1: 0.58 g / toluene / 2 h / Heating 8.1: OsO4 / tetrahydrofuran; H2O / 0.08 h 9.1: 0.65 g / sodium metaperiodate / tetrahydrofuran; H2O / 2.5 h 10.1: BuLi / hexane; tetrahydrofuran / 0.25 h / cooling 10.2: 60 percent / tetrahydrofuran; hexane / 0.25 h 11.1: 98 percent / H2 / chlorotris(triphenylphosphine)rhodium(I) / benzene; ethanol / 12 h 12.1: 83 percent / AcCl / methanol; CH2Cl2 / 2 h / 20 °C View Scheme