(2-甲基-3-丁烯基)苯合成路线 （共 16 条）
反应条件
Cs/Na/K alloy multistep reaction: 1.) THF, -75 deg C, 2 h, rate of cleavage relative to bibenzyl; Product distributionRate constant;
参考文献
Grovenstein, Erling; Bhatti, Amjad M.; Quest, Dean E.; Sengupta, Dibyendu; VanDerveer, Don
Journal of the American Chemical Society, 1983 , vol. 105, # 20 p. 6290 - 6299
反应条件
Cs/Na/K alloy multistep reaction: 1.) THF, -75 deg C, 2 h, rate of cleavage relative to bibenzyl; Product distributionRate constant;
参考文献
Journal of the American Chemical Society, , vol. 105, # 20 p. 6290 - 6299
反应条件
hydrogen; silica-supported dendrimer-palladium complex (G2-C6-Pd) in methanol
T=25°C; P=724.007 Torr; 9 h; Title compound not separated from byproducts;
参考文献
Zweni, Pumza P.; Alper, Howard
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 6 p. 725 - 731
反应条件
1: methanol / 0.5 h
2: 1.) sodium methoxide / 1.) methanol, 2.) vacuum pyrolysis
3: benzophenone / 0.25 h / Irradiation
View Scheme
参考文献
Creary, Xavier
Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1611 - 1618
反应条件
1: trimethylsilyl-methylmagnesium chloride With zinc(II) iodide in diethyl ether
Addition; 6 h; Heating;
2: 2-(1-methyl-2-phenyl-ethyl)-[1,3]dioxolane in benzene
Grignard reaction; 8 h; Heating; Further stages.;
参考文献
Chiang, Chao-Cheng; Chen, Yu-Huei; Hsieh, Yu-Tsai; Luh, Tien-Yau
Journal of Organic Chemistry, 2000 , vol. 65, # 15 p. 4694 - 4697
反应条件
in tetrahydrofuran
T=0°C; 0.5 h;
参考文献
Calo, Vincenzo; Lopez, Luigi; Pesce, Giannangelo; Calianno, Antonia
Journal of Organic Chemistry, 1982 , vol. 47, # 23 p. 4482 - 4485
反应条件
tri-n-butyl-tin hydride; 2,2'-azo-bisisobutyronitrile in benzene
T=80°C; 1.5 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ono, Noboru; Miyake, Hideyoshi; Kamimura, Akio; Hamamoto, Isami; Tamura, Rui; Kaji, Aritsune
Tetrahedron, 1985 , vol. 41, # 19 p. 4013 - 4024
反应条件
magnesium; CuCN in tetrahydrofuran
T=20°C; Barbier-type reaction; 1.5 h; Title compound not separated from byproducts.;
参考文献
Erdik, Ender; Kocoglu, Melike
Tetrahedron Letters, 2007 , vol. 48, # 24 p. 4211 - 4214
反应条件
1: 1.) sodium methoxide / 1.) methanol, 2.) vacuum pyrolysis
2: benzophenone / 0.25 h / Irradiation
View Scheme
参考文献
Creary, Xavier
Journal of the American Chemical Society, 1980 , vol. 102, # 5 p. 1611 - 1618
反应条件
3: Bu3SnH / AIBN / benzene / 1.5 h / 80 °C
View Scheme
参考文献
Ono, Noboru; Miyake, Hideyoshi; Kamimura, Akio; Hamamoto, Isami; Tamura, Rui; Kaji, Aritsune
Tetrahedron, 1985 , vol. 41, # 19 p. 4013 - 4024
