1-硝基-2-[(三氟甲基)硫代]苯合成路线 （共 15 条）
反应条件
tert.-butylnitrite; boron trifluoride diethyl etherate in acetonitrile T=50°C; Diazotization; Arylation; Trifluoromethylthiodediazoniation;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
反应条件
in acetonitrile T=50°C; Arylation; Trifluoromethylthiodediazoniation; 0.5 h;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
反应条件
tert.-butylnitrite in acetonitrile T=50°C; Diazotization; Arylation; Substitution;
参考文献
Adams, Dave J.; Goddard, Andrew; Clark, James H.; Macquarrie, Duncan J.
Chemical Communications, 2000 , # 11 p. 987 - 988
反应条件
in various solvent(s) T=150°C; 5 h; on alumina support;
参考文献
Clark, James H.; Craig, W. Jones; Kybett, Adrian P.; McClinton, Martin A.; Miller, Jack M.; et al.
Journal of Fluorine Chemistry, 1990 , vol. 48, # 2 p. 249 - 255
反应条件
in sulfolane T=180 - 230°C;
参考文献
Porter, Jason R.; Helmers, Mark R.; Wang, Ping; Furman, Jennifer L.; Joy, Stephen T.; Arora, Paramjit S.; Ghosh, Indraneel
Chemical Communications, 2010 , vol. 46, # 42 p. 8020 - 8022
反应条件
in further solvent(s) in N-methylpyrrolidone;
参考文献
Yagupol'skii, L. M.; Kondratenko, N. V.; Sanbur, V. P.
Synthesis, 1975 , p. 721 - 723
参考文献
Bayer Aktiengesellschaft
Patent: US6175042 B1, 2001 ;
反应条件
in acetonitrile 15 h; Inert atmosphereSealed tubeHeating;
参考文献
Weng, Zhiqiang; He, Weiming; Chen, Chaohuang; Lee, Richmond; Tan, Davin; Lai, Zhiping; Kong, Dedao; Yuan, Yaofeng; Huang, Kuo-Wei
Angewandte Chemie - International Edition, 2013 , vol. 52, # 5 p. 1548 - 1552
Angew. Chem., 2013 , vol. 125, # 5 p. 1588 - 1592
反应条件
ethanol; sulfuric acid; sodium nitrite
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
反应条件
1: concentrated H2SO4; HNO3 / Erhitzen des Reaktionsgemisches mit wss.-aethanol.KOH 2: ethanol; aqueous sodium nitrite solution; sulfuric acid View Scheme
参考文献
Jagupol'skii; Marenez
Zhurnal Obshchei Khimii, 1956 , vol. 26, p. 101,104; engl. Ausg. S. 99, 101
