(Z)-5-十二碳烯-7-炔合成路线 （共 10 条）
反应条件
titanium(IV) isopropylate; iso-propylmagnesium bromide in diethyl ether
T=-78 - -50°C; Inert atmosphere;
参考文献
Lueken, Christian; Moberg, Christina
Organic Letters, 2008 , vol. 10, # 12 p. 2505 - 2508
反应条件
NH4BF4; [η5-C5H5RuCl(μ2SMe)2Ruη5-C5H5Cl] in methanol
T=60°C; 18 h;
参考文献
Que, Jing-Ping; Masui, Dai; Ishii, Youichi; Hidai, Masanobu
Chemistry Letters, 1998 , # 10 p. 1003 - 1004
反应条件
benzene-d6; 2-[bis(pentafluorophenyl)boryl]-N,N-dimethylaniline; hydrogen
T=120°C; P=1650.17 Torr; 10 h; Schlenk technique;
参考文献
Chernichenko, Konstantin; Madarasz, Adam; Papai, Imre; Nieger, Martin; Leskelae, Markku; Repo, Timo
Nature Chemistry, 2013 , vol. 5, # 8 p. 718 - 723
反应条件
[(Et2N)3U][BPh4]; tert-butylamine in benzene
T=60°C; 6 h;
参考文献
Wang, Jiaxi; Dash, Aswini Kumar; Kapon, Moshe; Berthet, Jean-Claude; Ephritikhine, Michel; Eisen, Moris S.
Chemistry - A European Journal, 2002 , vol. 8, # 23 p. 5384 - 5396
反应条件
(hydridotris(pyrazolyl)borate)Ru(H)(triphenylphospine)2 in toluene
T=111°C; 20 h; Yield given. Yields of byproduct given;
参考文献
Slugovc, Christian; Doberer, Daniel; Gemel, Christian; Schmid, Roland; Kirchner, Karl; Winkler, Berthold; Stelzer, Franz
Monatshefte fur Chemie, 1998 , vol. 129, # 3 p. 221 - 233
反应条件
lithium diisopropyl amide in tetrahydrofuran; hexane
1.) -78 deg C, 1 h; 2.) -78 deg C, 3 h then rt., 1 h;
参考文献
Baudin, J. B.; Hareau, G.; Julia, S. A.; Lorne, R.; Ruel, O.
Bulletin de la Societe Chimique de France, 1993 , vol. 130, p. 856 - 878
反应条件
in tetrahydrofuran
T=25°C; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Zhang, Yantao; Miller, Joseph A.; Negishi, Ei-ichi
Journal of Organic Chemistry, 1989 , vol. 54, # 9 p. 2043 - 2044
反应条件
furan-2-yl-lithium; triphenylphosphine; palladium dichloride
参考文献
Murahashi,S.-I. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 14 p. 2408 - 2417
反应条件
in tetrahydrofuran
T=-78°C;
参考文献
Wang, Youliang; Yepremyan, Akop; Ghorai, Subir; Todd, Robert; Aue, Donald H.; Zhang, Liming
Angewandte Chemie - International Edition, 2013 , vol. 52, # 30 p. 7795 - 7799
Angew. Chem., 2013 , vol. 125, # 30 p. 7949 - 7953
反应条件
(i) CuI, Me2NCH2CH2NMe2, (ii) /BRN= 1740148/; Multistep reaction;
参考文献
Alexakis,A. et al.
Synthesis, 1979 , p. 826 - 830
