in further solvent(s) equilibrium in azoisobutyric acid dinitrile at 40°C; examination with NMR-spectroscopy;;
参考文献
Creemers, H. M. J. C.; Verbeek, F.; Noltes, J. G.
Journal of Organometallic Chemistry, 1967 , vol. 8, p. 469 - 477
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Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.6, page 17 - 18
Pollard, F. H.; Nickless, G.; Cooke, D. J.
Journal of Chromatography, 1965 , vol. 17, p. 472 - 482
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Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.5, page 16 - 16
in neat (no solvent) Irradiation (UV/VIS); under N2, ratio Me3SnH : olefin = 1.5:1, olefin added to Me3SnH, stirred for 240 min at 25°C; followed by IR and NMR, elem. anal.;
参考文献
Chopa, Alicia B.; Koll, Liliana C.; Savini, Monica C.; Podesta, Julio C.; Neumann, Wilhelm P.
Organometallics, 1985 , vol. 4, p. 1036 - 1041
in cyclohexane equilibrium at 40°C; examination with NMR-spectroscopy;;
参考文献
Creemers, H. M. J. C.; Verbeek, F.; Noltes, J. G.
Journal of Organometallic Chemistry, 1967 , vol. 8, p. 469 - 477
Full Text Show Details
Gmelin Handbook: Sn: Org.Verb.4, 1.2.1.1.1.4.6, page 17 - 18
lithium aluminium tetrahydride in not given Irradiation (UV/VIS); UV-irradiation of (CH3)3SnCH(CH3)CH2CH3 and CH3CHCHCOOC10H19; reduction with LiAlH4;;
in neat (no solvent) condensing of equimolar amts. of tinhydride and SiClHBr2 (trace of SiCl2HBr present) into cold finger, reaction at room temp. (30 min); further products; not isolated; IR spectroscopy;
in neat (no solvent) inert atmosphere (N2, Ar or high vac.), room temperature, equimolar amts. of halosilane/tinhydride, reactn. time 12 h; not isolated; IR spectroscopy (identified 41percent SiCl2H2 and 15percent SiH4 in product mixt.);
