1-氯-2-(2-丙烯-1-基)-苯合成路线 (共 11 条)
反应条件
dimethyl(n-butyl)amine; tetrabutyl-ammonium chloride; palladium on activated charcoal in water; N,N-dimethyl-formamide T=180°C; 3 h;
参考文献
Mariampillai, Brian; Herse, Christelle; Laufens, Mark
Organic Letters, 2005 , vol. 7, # 21 p. 4745 - 4747
反应条件
1: ortho-iodochlorobenzene With diethylzinc in hexane; N,N-dimethyl-formamide T=20°C; 5 h; 2: allyl bromide in hexane; N,N-dimethyl-formamide T=20°C; 20 h; Further stages.;
参考文献
Ueno, Masahiro; Wheatley, Andrew E. H.; Kondo, Yoshinori
Chemical Communications, 2006 , # 33 p. 3549 - 3550
反应条件
tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether; water 6 h; Reflux;
参考文献
Nishiwaki, Nagatoshi; Kamimura, Ryuichiro; Shono, Kimihiro; Kawakami, Toshihiko; Nakayama, Katsuhisa; Nishino, Kohei; Nakayama, Takayuki; Takahashi, Keisuke; Nakamura, Aki; Hosokawa, Takahiro
Tetrahedron Letters, 2010 , vol. 51, # 27 p. 3590 - 3592
参考文献
Wang, I-Hsiung; Dobson, Gerard R.
Journal of Organometallic Chemistry, 1988 , vol. 356, p. 77 - 84
反应条件
magnesium 1) ether, reflux, 1 h, 2) ether, 25 deg C, overnight; Yield given. Multistep reaction;
参考文献
Padwa, Albert; Hornbuckle, Susan F.; Fryxell, Glen E.; Zhang, Zhijia J.
Journal of Organic Chemistry, 1992 , vol. 57, # 21 p. 5747 - 5757
反应条件
aluminum oxide; silica gel; potassium carbonate; zinc(II) chloride T=50°C; 24 h;
参考文献
Kodomari, Mitsuo; Nawa, Satoru; Miyoshi, Tadahiro
Journal of the Chemical Society, Chemical Communications, 1995 , # 18 p. 1895 - 1896
反应条件
1 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Ochial; Fujita; Arimoto; Yamaguchi
Chemical and Pharmaceutical Bulletin, 1983 , vol. 31, # 1 p. 86 - 93
反应条件
hexafluoroisopropyl alcohol; palladium diacetate T=20°C; 24 h; Inert atmosphere; optical yield given as percent de;
参考文献
Nishiwaki, Nagatoshi; Kamimura, Ryuichiro; Shono, Kimihiro; Kawakami, Toshihiko; Nakayama, Katsuhisa; Nishino, Kohei; Nakayama, Takayuki; Takahashi, Keisuke; Nakamura, Aki; Hosokawa, Takahiro
Tetrahedron Letters, 2010 , vol. 51, # 27 p. 3590 - 3592
反应条件
magnesium
1.) THF, 7h, reflux, 2.) ether, -78 deg C; Yield given. Multistep reaction;
参考文献
Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.
Journal of Organic Chemistry, 1984 , vol. 49, p. 1353 - 1360
反应条件
magnesium
1.) THF, 7h, reflux, 2.) ether, -78 deg C; Yield given. Multistep reaction;
参考文献
Padwa, Albert; Rieker, William F.; Rosenthal, Robert J.
Journal of Organic Chemistry, 1984 , vol. 49, p. 1353 - 1360