反式-1,2-二氯乙烯合成路线 （共 182 条）
反应条件
in benzene
T=70°C; 48 h; Product distributionMechanism;
参考文献
Lambert; Bosch; Mueller; Kobayashi
Journal of the American Chemical Society, 1984 , vol. 106, # 12 p. 3584 - 3589
反应条件
in benzene
T=70°C; 24 h; var. solvents, var. additives; Product distributionMechanism;
参考文献
Lambert, Joseph B.; Boch, Richard J.; Larson, Eric G.
Journal of Organic Chemistry, 1985 , vol. 50, # 17 p. 3054 - 3059
反应条件
trichlorosilane
T=610°C;
参考文献
Agre; Hilling
Journal of the American Chemical Society, 1952 , vol. 74, p. 3895,3898
反应条件
1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane
T=0°C;
2: benzaldehyde in tetrahydrofuran; hexane
T=0°C;
3: trimethylsilyl trifluoromethanesulfonate Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
反应条件
1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane
T=0°C;
2: benzaldehyde in tetrahydrofuran; hexane
T=0°C; Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
反应条件
1: trans-1,2-dichloroethylene With n-butyllithium in tetrahydrofuran; hexane
T=0°C;
2: benzaldehyde in tetrahydrofuran; hexane
T=0°C;
3: trimethylsilyl trifluoromethanesulfonate Further stages;
参考文献
Nagaki, Aiichiro; Matsuo, Chika; Kim, Songhee; Saito, Kodai; Miyazaki, Atsuo; Yoshida, Jun-Ichi
Angewandte Chemie - International Edition, 2012 , vol. 51, # 13 p. 3245 - 3248
反应条件
piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) in diethyl ether
T=20°C; 2 h;
参考文献
Nakamura, Masaharu; Endo, Kohei; Nakamura, Eiichi
Advanced Synthesis and Catalysis, 2005 , vol. 347, # 11-13 p. 1681 - 1686
反应条件
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-butylamine in benzene
T=23°C; 5 h; Inert atmosphere;
参考文献
Qian, Mingxing; Negishi, Ei-Ichi
Organic Process Research and Development, 2003 , vol. 7, # 3 p. 412 - 417
反应条件
Ni(PPh3)4 in hexane; benzene
T=20°C; 6 h; further catalyst: palladium tetrakis (triphenylphosphine);
参考文献
Ratovelomanana, Victorin; Linstrumelle, Gerard
Tetrahedron Letters, 1984 , vol. 25, # 52 p. 6001 - 6004
反应条件
piperidine; copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride in diethyl ether
T=20°C; 4 h;
参考文献
Hamze, Abdallah; Provot, Olivier; Brion, Jean-Daniel; Alami, Mouad
Journal of Organic Chemistry, 2007 , vol. 72, # 10 p. 3868 - 3874
