(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether
20 h; Ambient temperature;
参考文献
Hayashi, Tamio; Konishi, Mitsuo; Kobori, Yuji; Kumada, Makoto; Higuchi, Taiichi; Hirotsu, Ken
Journal of the American Chemical Society, 1984 , vol. 106, p. 158 - 163
1: sec-butylmagnesium chloride With indium(III) chloride in tetrahydrofuran; hexane
T=-78 - 20°C;
2: carbon monoxide; E-styryl bromide With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane
T=60°C; 6 h;
参考文献
Lee, Sung Wook; Lee, Kooyeon; Seomoon, Dong; Kim, Sundae; Kim, Hyunseok; Kim, Hyun; Shim, Eunkyong; Lee, Miae; Lee, Seokju; Kim, Misook; Lee, Phil Ho
Journal of Organic Chemistry, 2004 , vol. 69, # 14 p. 4852 - 4855
1: sec-butylmagnesium chloride With zinc(II) chloride in tetrahydrofuran
T=20°C; 0.333333 h;
2: 1-chloro-4-(1,1-dimethylethyl)-1-cyclohexene With 1-methyl-pyrrolidin-2-one; Pd0(tris(tert-butyl)phosphine)2 in tetrahydrofuran
T=100°C; Negishi reaction; 5 h; Further stages. Title compound not separated from byproducts.;
参考文献
Dai; Fu
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2719 - 2724
