in dimethyl sulfoxide T=25°C; kinetic of reactions of cyclic secondary amines (pyrrolidine, piperidine) with 2,4-dinitro-1-naphthyl ethyl ether in DMSO; stage I kinetics and equilibrium (with piperidine); Rate constantEquilibrium constantMechanism;
参考文献
Bunnett, Joseph F.; Sekiguchi, Shizen; Smith, Lewis A.
Journal of the American Chemical Society, 1981 , vol. 103, # 16 p. 4865 - 4871