ClO2(1-); sodium bromite in water Kinetics; byproducts: H2O; ClO2 disproprotionated in H2O soln. in presence of NaBrO2 and ClO2(1-) at 25°C; monotored by stopped-flow spectrophotometry;
参考文献
Wang, Lu; Nicoson, Jeffrey S.; Huff Hartz, Kara E.; Francisco, Joseph S.; Margerum, Dale W.
Inorganic Chemistry, 2002 , vol. 41, # 1 p. 108 - 113
N-tert-butyl-α-phenyl nitrone in water Kinetics; react. of ClO2 in H2O with excess azide at 25.degreee.C in the presence of the spin trap at pH ca 7, maintaining of ionic strength at 0.10 M by addn. of NaClO4; not isolated; monitored by spectrophotometry at 360 nm;;
参考文献
Awad; Stanbury
Journal of the American Chemical Society, 1993 , vol. 115, # 9 p. 3636 - 3642
methyltrioxorhenium (VII) in water Kinetics; 0.1 M CF3SO3H, 25°C; treatment of CH3ReO3 with H3PO2 (UV-monitoring), then addn. of chlorate; not isolated, reaction followed by UV/VIS spectroscopy;
参考文献
Abu-Omar, Mahdi M.; Appelman, Evan H.; Espenson, James H.
Inorganic Chemistry, 1996 , vol. 35, # 26 p. 7751 - 7757
