(2,2-联吡啶)二氯钯(II)合成路线 （共 41 条）
反应条件
sodium chloride in methanol; water
参考文献
WO2005/858 A2, ;
Page/Page column 11 ;
反应条件
in hydrogenchloride; ethanol addn. of ethanolic soln. of 2,2'-bipyridyl to soln. of K2PdCl4 in aq. HCl with stirring, boiled for 2 h; washed with water, ethanol, acetone and diethyl ether, dried at 100°C; elem. anal.;
参考文献
Polyhedron, , vol. 7, p. 349 - 352
反应条件
NaCl in ethanol warming soln. of PdCl2(PC6H5(C5H4N)2)2 and satd. aq. NaCl in 95 percent ethanol at 50-60°C for 18 h, concentration in vac.;; dissolving in CH2Cl2, filtration, concentration;;
参考文献
Inorganic Chemistry, , vol. 26, p. 3500 - 3506
反应条件
HCl in water Electrochem. Process; electrolysis of Pd-foil at 3 V for 60 min; HCl containing bipyridyl as electrolyte; filtn., elem. anal.;
参考文献
Polyhedron, , vol. 11, p. 3191 - 3196
反应条件
nitrogen in tetrahydrofuran byproducts: CuCl; Pd-compd. in THF and CuCl2(BuNH2)2 in a Cu/Pd molar ratio of 4:1 are loaded sep. in the 2 branches of an inverted-Y glass reactor. Reactor is closed under N2, contents are mixed and stirred for 1 h.; IR, GC-MS and GLC anal. of liq. phase shows presence of BuNH2COOCH3. Filtn. of solid residue (anaerobic conditions), sepn. of PdCl2(bipy) from CuCl by addn. of MeOH soln. contg. bipy, IR, elem. anal. Removal of MeOH(vac.) gives CuCl(bipy). Elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 470, # 1.2 p. 249 - 252
反应条件
[2,2']bipyridinyl in dichloromethane N2-atmosphere; addn. of 2 equiv. of pentyne derivative to Pd-complex soln. (0°C), addn. of 2 equiv. bipy; filtration off of Pd(bipy)Cl2, evapn. of filtrate to dryness (reduced pressure), washing (Et2O), crystn. (CH2Cl2/light petroleum);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 167 - 177
反应条件
2,2'-bipyridyl in methanol byproducts: KCl;
参考文献
Acta Crystallographica, Section C: Crystal Structure Communications, , vol. 43, p. 1064 - 1067
反应条件
in dimethyl sulfoxide 100°C, 50 min; monitored by (1)H NMR;
参考文献
Polyhedron, , vol. 40, # 1 p. 168 - 174
反应条件
AgBF4 or NaBF4 in not given
参考文献
Polyhedron, , vol. 29, p. 2318 - 2323
反应条件
1: toluene 2: 1,2-dichloro-ethane 3: dichloromethane View Scheme
参考文献
Organometallics, , vol. 20, # 6 p. 1109 - 1114
