氯化三(三苯基膦)合铑(I)合成路线 （共 95 条）
反应条件
diphenylphosphoranyl azide; triphenylphosphine in tetrahydrofuran byproducts: N2, diphenylphosphoryl isocyanate; (N2); a soln. of Rh-complex and diphenylphosphoryl azide stirred for 1 h; P(C6H5)3 added; evapd.; ethanol added; refluxed for 1 h; filtered; washed with ethanol; dried in vacuo;
参考文献
Inorganic Chemistry, , vol. 32, p. 1866 - 1867
反应条件
triphenylphosphine in ethanol 10-fold excess PPh3; refluxing; recrystn. from C6H6/C6H14;;
参考文献
Journal of Organometallic Chemistry, , vol. 359, p. C22 - C26
反应条件
triphenylphosphine in benzene 2 equiv of PPh3 were added to a stirred benzene soln. of Rh-complex under inert atmosphere, the soln. was left to stand for 1 week at 35°C; crystals were isolated from the soln. on cooling;
参考文献
Murray, Brendan D.; Hope, Hakon; Hvoslef, Jan; Power, Philip P.
Organometallics, 1984 , vol. 3, p. 657 - 663
反应条件
triphenylphosphine in benzene Kinetics; byproducts: CO; Irradiation (UV/VIS); flash photolysis: addn. of degassed and distd. solvent into the photolysis cell containing the metal complex, photolysis in presence of PPh3 at 23+/-2°C (λ >315 nm) under Ar; reversible process; not isolated, detd. by NMR;
参考文献
Journal of the American Chemical Society, , vol. 109, # 2 p. 436 - 442
反应条件
in ethanol 0.00416667 h; Schlenk techniqueInert atmosphere;
参考文献
Catalysis Today, , vol. 200, # 1 p. 54 - 62
反应条件
1: PPh3 / benzene 2: PPh3 / acetonitrile; benzene 3: chlorobenzene View Scheme
参考文献
Journal of the American Chemical Society, , vol. 127, # 43 p. 15304 - 15321
反应条件
1: PPh3 / acetonitrile; benzene 2: chlorobenzene View Scheme
参考文献
Journal of the American Chemical Society, , vol. 127, # 43 p. 15304 - 15321
反应条件
1: diethyl ether 2: PPh3 / benzene 3: PPh3 / acetonitrile; benzene 4: chlorobenzene View Scheme
参考文献
Journal of the American Chemical Society, , vol. 127, # 43 p. 15304 - 15321
反应条件
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8) addn. of 3 equiv. of PPh3 to soln. of Rh-complex (25°C, NMR tube), (31)P-NMR monitoring at -40°C; not isolated;
参考文献
Journal of the American Chemical Society, , vol. 114, # 24 p. 9350 - 9359
反应条件
P(C6H5)3 in THF-d8 (tetrahydrofuran-d8) react. for 4 h; monitored by (11)B-NMR spectroscopy;
参考文献
Journal of the American Chemical Society, , vol. 114, # 24 p. 9350 - 9359
