三(2-氰乙基)硝基甲烷合成路线 （共 10 条）
反应条件
potassium hydroxide; tetra(n-butyl)ammonium hydrogensulfate in 1,4-dioxane; water T=80 - 85°C;
参考文献
Newkome, George R.; Moorefield, Charles N.; Theriot, Kevin J.
Journal of Organic Chemistry, 1988 , vol. 53, # 23 p. 5552 - 5554
反应条件
Reaktion des Kalium-Salzes;
参考文献
Herzog et al.
Journal of the American Chemical Society, 1951 , vol. 73, p. 749
反应条件
in Gegenwart von alkal.Katalysatoren;
参考文献
I.G.Farbenind.
Patent: DE728531 , 1940 ;
DRP/DRBP Org.Chem.
参考文献
Fort; McLean
Journal of the Chemical Society, 1948 , p. 1907
反应条件
hydrogenchloride 0.75 h; Heating;
参考文献
Newkome, George R.; Moorefield, Charles N.; Theriot, Kevin J.
Journal of Organic Chemistry, 1988 , vol. 53, # 23 p. 5552 - 5554
反应条件
1: 94 percent / conc. HCl / 0.75 h / Heating 2: 95 percent / BH3 / tetrahydrofuran / 0.5 h / 25 °C 3: 82 percent / H2 / T-1 Raney Ni / ethanol / 72 h / 25 °C / 2280 Torr View Scheme
参考文献
Journal of Organic Chemistry, , vol. 53, # 23 p. 5552 - 5554
反应条件
1: 94 percent / conc. HCl / 0.75 h / Heating 2: 95 percent / BH3 / tetrahydrofuran / 0.5 h / 25 °C View Scheme
参考文献
Newkome, George R.; Moorefield, Charles N.; Theriot, Kevin J.
Journal of Organic Chemistry, 1988 , vol. 53, # 23 p. 5552 - 5554
反应条件
2,2'-azo-bisisobutyronitrile; tri-n-butyl-tin hydride in 1,2-dichloro-ethane
1.5 h; Heating;
参考文献
Yamagiwa, Yoshiro; Koreishi, Yoshiro; Kiyozumi, Satoshi; Kobayashi, Masanori; Kamikawa, Tadao; Tsukino, Mitsuji; Goi, Hironori; Yamamoto, Mikiko; Munakata, Megumu
Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 11 p. 3317 - 3323
反应条件
1: 90 percent / tributyltinhydride, azobisisobutyronitrile / 1,2-dichloro-ethane / 1.5 h / Heating
2: HCl / 3 h / Heating
3: LiAlH4 / tetrahydrofuran / 2 h / Heating
4: 84 percent / HBr/AcOH / 3 h / Heating
View Scheme
参考文献
Yamagiwa, Yoshiro; Koreishi, Yoshiro; Kiyozumi, Satoshi; Kobayashi, Masanori; Kamikawa, Tadao; Tsukino, Mitsuji; Goi, Hironori; Yamamoto, Mikiko; Munakata, Megumu
Bulletin of the Chemical Society of Japan, 1996 , vol. 69, # 11 p. 3317 - 3323
反应条件
1: 89 percent / Tributylzinnhydrid, Azoisobutyronitril / benzene / 12 h / Heating
2: 25percent aq. HCl / 0.75 h / Heating
View Scheme
参考文献
Karunaratne; Hoveyda; Orvig
Tetrahedron Letters, 1992 , vol. 33, # 14 p. 1827 - 1830
