1,4-二碘-2,5-二(辛基氧基)苯合成路线 （共 10 条）
反应条件
KIO3; iodine; acetic acid
参考文献
Hou, Jiali; Song, Fengyan; Wang, Lu; Wei, Guo; Cheng, Yixiang; Zhu, Chengjian
Macromolecules, 2012 , vol. 45, # 19 p. 7835 - 7842,8
反应条件
potassium hydroxide in dimethyl sulfoxide; acetone 24 h; RefluxInert atmosphereSchlenk technique;
参考文献
Pasquini, Chiara; Coniglio, Alessandra; Bassetti, Mauro
Tetrahedron Letters, 2012 , vol. 53, # 46 p. 6191 - 6194,4
反应条件
1: 90 percent / K2CO3 / dimethylformamide / 24 h / 80 °C 2: 59 percent / I2; KIO3; aq. H2SO4 / acetic acid / 24 h / 80 °C View Scheme
参考文献
Dixon, Sally; Whitby, Richard J.
Tetrahedron Letters, 2006 , vol. 47, # 46 p. 8147 - 8150
反应条件
1: 90 percent / K2CO3 / dimethylformamide / 24 h / 80 °C 2: 59 percent / I2; KIO3; aq. H2SO4 / acetic acid / 24 h / 80 °C View Scheme
参考文献
Gu, Tao; Nierengarten, Jean-Francois
Tetrahedron Letters, 2001 , vol. 42, # 18 p. 3175 - 3178
反应条件
1: KOH / dimethylsulfoxide 2: I2; IO3- View Scheme
参考文献
Wang, Shujun; Oldham Jr., Warren J.; Hudack Jr., Raymond A.; Bazan, Guillermo C.
Journal of the American Chemical Society, 2000 , vol. 122, # 24 p. 5695 - 5709
反应条件
1: boron tribromide / dichloromethane / 20 °C / |Inert atmosphere; |Schlenk technique 2: potassium hydroxide / acetone; dimethyl sulfoxide / 24 h / |Reflux; |Inert atmosphere; |Schlenk technique View Scheme
参考文献
Pasquini, Chiara; Coniglio, Alessandra; Bassetti, Mauro
Tetrahedron Letters, 2012 , vol. 53, # 46 p. 6191 - 6194,4
反应条件
1: 2,5-diiodo-1,4-bis(n-octyloxy)benzene With n-butyllithium in diethyl ether T=0°C; 0.25 h; 2: N,N-dimethyl-formamide in diethyl ether T=0 - 20°C; 2 h;
参考文献
Park, Moo-Jin; Jonghee; Hwan Jung; Park, Jong-Hwa; Kong, Hoyoul; Ji-Young; Hwang, D.O.-Hoon; Shim, Hong-K.U.
Journal of Polymer Science, Part A: Polymer Chemistry, 2010 , vol. 48, # 1 p. 82 - 90
反应条件
1: With tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane 0.333333 h; Heating; 2: With lithium diisopropyl amide in 1,4-dioxane T=0°C; 3: With palladium in 1,4-dioxane T=110°C; 1 h;
参考文献
Pizzoferrato; Berliocchi; Di Carlo; Lugli; Venanzi; Micozzi; Ricci; Lo Sterzo
Macromolecules, 2003 , vol. 36, # 7 p. 2215 - 2223
反应条件
tetrakis(triphenylphosphine) palladium(0) in 1,4-dioxane 0.333333 h; Heating; Title compound not separated from byproducts;
参考文献
Pizzoferrato; Berliocchi; Di Carlo; Lugli; Venanzi; Micozzi; Ricci; Lo Sterzo
Macromolecules, 2003 , vol. 36, # 7 p. 2215 - 2223
反应条件
1: 2,5-diiodo-1,4-bis(n-octyloxy)benzene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; 2: N,N-dimethyl-formamide in tetrahydrofuran; hexane T=-78°C; 2 h;
参考文献
Liao, Jian; Wang, Qing
Macromolecules, 2004 , vol. 37, # 18 p. 7061 - 7063
