in benzene Irradiation (UV/VIS); (CH3)2GeCH2Ge(CH3)2Fe(CO)4 and (CH3)3GeH in C6H6 irradiated in a quartz tube (Hg lamp, 20h); determination of content: 1H-NMR, GC-MS, not isolated;
vaporization of Ge (1200-1300°C, alumina-coated tungsten crucible, 5E-3 Torr), cocondensated with Me3GeH (liq. N2 cooling), warming if cocondensate to room temp., standing (1.5 h); GC-MS, GLC;
参考文献
Bulletin of the Chemical Society of Japan, , vol. 61, p. 1789 - 1790
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反应条件
in neat (no solvent) byproducts: propene, methane; hydride condensed onto palladium complex at 77 K and warmed slowly to room temp.; volatile products separated by trap-to-trap fractional distillation at 298 K, 253 K, 153 K and 77 K, fractions collected at each temp. dissolved in ether and solns. passed through gas chromatograph;
参考文献
Ssebuwufu, P. John; Glockling, F.; Harriott, P.
Inorganica Chimica Acta, 1985 , vol. 98, p. L35 - L38
