1,2-环氧-3-甲基丁烷合成路线 (共 27 条)
反应条件
3-chloro-benzenecarboperoxoic acid in 1,2-dichloro-benzene T=0 - 20°C; 19 h; Inert atmosphere;
参考文献
Nacsa, Eric D.; Lambert, Tristan H.
Organic Letters, 2013 , vol. 15, # 1 p. 38 - 41
反应条件
1: aluminium oxide / 540 °C 2: peroxybenzoic acid; chloroform View Scheme
参考文献
Recueil des Travaux Chimiques des Pays-Bas, , vol. 45, p. 842
反应条件
sodium tungstate; dihydrogen peroxide; benzyltrioctylammonium chloride T=60°C; P=2250.2 Torr; 5 h; hydroperoxide and peroxide epoxidation/hydroxylation; other interphase transfer catalysts, other organic hydroperoxides; Product distribution;
参考文献
Petroleum Chemistry (English Translation), , vol. 34, # 4 p. 365 - 372
Neftekhimiya, , vol. 34, # 4 p. 376 - 382
反应条件
air; alpha,alpha-dimethylbenzyl hydroperoxide T=100°C; P=15001.2 Torr; 2 h; also in the presence of Mo, Co and V-binetallic catalyst system; Product distribution;
参考文献
Petroleum Chemistry (English Translation), , vol. 34, # 4 p. 357 - 364
Neftekhimiya, , vol. 34, # 4 p. 368 - 375
反应条件
magnesium bromide in N,N-dimethyl-formamide T=130°C; 0.666667 h; Further byproducts given;
参考文献
Petroleum Chemistry, , vol. 43, # 3 p. 167 - 169
反应条件
magnesium bromide in N,N-dimethyl-formamide T=130°C; 0.666667 h; Further byproducts given;
参考文献
Petroleum Chemistry, , vol. 43, # 3 p. 167 - 169
反应条件
2,2,6,6-tetramethylpiperidinyl-lithium in diethyl ether; hexane T=0 - 20°C; 2 h; Product distribution; Further Variations:Solvents;
参考文献
Journal of Organic Chemistry, , vol. 72, # 13 p. 4763 - 4773
反应条件
trilithium phosphate in gas T=303°C; var. temperatures; Product distributionMechanism;
参考文献
Petroleum Chemistry, , vol. 36, # 6 p. 540 - 546
反应条件
enantiomeric resolution by complexation gas chromatography on bis<(1R)-3-(heptafluorobutyryl)camphorates> of Ni(II), Co(II), Mn(II) in squalane at 60 deg C, separation factors, thermodynamic parameters of enantiomer discrimination (-Δ(ΔG0)); Thermodynamic data;
参考文献
Schurig,V.; Buerkle,W.
Journal of the American Chemical Society, 1982 , vol. 104, p. 7573
反应条件
magnesium bromide in N,N-dimethyl-formamide T=130°C; 0.666667 h; Further byproducts given;
参考文献
Petroleum Chemistry, , vol. 43, # 3 p. 167 - 169