苯(甲)醛-2,3,4,5,6-d5合成路线 (共 15 条)
反应条件
1: benzene-d6 With n-butyllithium; potassium tert-butylate in hexane 1 h; 2: N,N-dimethyl-formamide in hexane
参考文献
Griesbeck, Axel G.; Bondock, Samir; Cygon, Peter
Journal of the American Chemical Society, 2003 , vol. 125, # 30 p. 9016 - 9017
反应条件
1: 83 percent / lithium aluminum deuteride / tetrahydrofuran; diethyl ether / 16 h / 40 °C 2: 84 percent / pyridinium chlorochromate / CH2Cl2 / 1 h / 20 °C View Scheme
参考文献
Yamataka, Hiroshi; Sasaki, Daizo; Kuwatani, Yoshiyuki; Mishima, Masaaki; Tsuno, Yuho
Journal of the American Chemical Society, 1997 , vol. 119, # 42 p. 9975 - 9979
反应条件
1: With titanium tetrachloride in dichloromethane T=0 - 20°C; 2: With water in dichloromethane Cooling with ice;
参考文献
Chen, Yihui; Herrmann, Rolf; Fishkin, Nathan; Henklein, Peter; Nakanishi, Koji; Ernst, Oliver P.
Photochemistry and Photobiology, 2008 , vol. 84, # 4 p. 831 - 838
反应条件
1: Mg 2: borane 3: pyridinium dichromate View Scheme
参考文献
Yamataka, Hiroshi; Sasaki, Daizo; Kuwatani, Yoshiyuki; Mishima, Masaaki; Tsuno, Yuho
Journal of the American Chemical Society, 1997 , vol. 119, # 42 p. 9975 - 9979
反应条件
1: bromobenzene-d5 With n-butyllithium T=-78°C; 2: N,N-dimethyl-formamide 3: With hydrogenchloride in water
参考文献
Ekhato, I. Victor; Liao, Yuan; Plesescu, Mihaela
Journal of Labelled Compounds and Radiopharmaceuticals, 2004 , vol. 47, # 12 p. 821 - 835
反应条件
n-butyllithium; potassium tert-butylate 1) hexane, 3h; Yield given. Multistep reaction;
参考文献
Schlosser, Manfred; Choi, Jung Hoon; Takagishi, Sadahito
Tetrahedron, 1990 , vol. 46, # 16 p. 5633 - 5648
参考文献
Hazai, L.; Deak, Gy.; Toth, G.; Volford, J.; Tamas, J.
Journal of Heterocyclic Chemistry, 1982 , vol. 19, p. 49 - 53
反应条件
Irradiation; Mechanism;
参考文献
Hu, Shengkui; Neckers, Douglas C.
Journal of Materials Chemistry, 1997 , vol. 7, # 9 p. 1737 - 1740
反应条件
sodium hydroxide in methanol 132 h;
参考文献
Hege; Weymann; Lietz
Arzneimittel-Forschung/Drug Research, 1984 , vol. 34, # 8 p. 843 - 849
参考文献
Baether, Wolfgang; Kuck, Dietmar; Gruetzmacher, Hans-Fr.
Organic Mass Spectrometry, 1985 , vol. 20, # 9 p. 572 - 577