bis(trichlorophosphine)iminium hexachlorophosphate in 1,1,2,2-tetrachloroethylene; n-heptane T=25°C; various reagent concentrations, other reagent; Rate constant;
参考文献
Journal of Organometallic Chemistry, , vol. 526, # 2 p. 351 - 361
water byproducts: C2H5OH; addn. of H2O that contained NaOH to a mixt. of (CH3)2Si(OC2H5)2 and (CH3)3Si(OC2H5) (1:1 mol) at 40°C; boiling after addn. of a 20percent excess of H2O;; evapn. of C2H5OH; distillation gives linear polymers (CH3)3Si((CH3)2SiO)(0-13)Si(CH3)3; higher polymers as residue (not distillable);;
