sodium tetrahydroborate; hydrogen; PdCl2 complex on modified silca gel in methanol T=20°C; P=760 Torr; hydrogenolysis of chlorobenzenes in the presence of palladium chloride complex deposited on modified silica gel; effect of the nature of substituents in aromatic ring; Rate constant;
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 29, # 1 p. 99 - 101
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , # 1 p. 114 - 117
sodium hydroxide; N-hexadecyl-N,N,N-trimethylammonium bromide in methanol; water T=68.5°C; other N-methyl-N-arylcarbamates; reaction in absence of cetyltrimethylammonium bromide; Rate constantMechanism;
参考文献
Australian Journal of Chemistry, , vol. 36, # 11 p. 2203 - 2209