1,1,2,2-四氯-二硼烷合成路线 （共 63 条）
反应条件
in neat (no solvent) in a Pyrex tube, 3 min at 450°C; monitored by (11)B NMR and ESR;
参考文献
Inorganic Chemistry, , vol. 25, p. 2366 - 2372
反应条件
in hexane byproducts: H2; 0 °C; equimolar amts. of B2Cl4 and (C5H5)2Fe; 60 h; traces of HBCl2 detected in gas phase react. products;
参考文献
Inorganic Chemistry, , vol. 9, p. 1661,1664
B: B-Verb.9, 1.2.2.1, page 15 - 20
反应条件
in neat (no solvent) in a Pyrex tube, 0.75-1 h at 350-400°C; monitored by (11)B NMR and ESR;
参考文献
Inorganic Chemistry, , vol. 25, p. 2366 - 2372
反应条件
room temp.; IR bands of B2H5Cl obsd. after 5 min intensity maximum after 64.5 h;
参考文献
B: B-Verb.9, 2.1.2.1, page 45 - 47
Diss. Abstr., Thesis Pennsylvania State Univ. 1961 , vol. 22, p. 86/7
反应条件
sodium allene and B2Cl4 in 1:2 mole ratio;
参考文献
Abstr. Papers 160th Natl. Meeting Am. Chem. Soc., Chicago, III., 1970, INOR 64
Diss. Abstr. Intern. B, Diss. Pennsylvania State Univ. 1970 , vol. 32, p. 173
反应条件
in neat (no solvent) (vac. or inert gas); B2Cl4 and PCl3 condensed in vac., sealed, heated at 400°C for 1 h, allowed to cool over 20 h; vac.-evapd. at 0°C, extd. with BCl3, evapd. at 0°C, fractionated by sublimation in vac.;
参考文献
Inorganic Chemistry, , vol. 39, # 6 p. 1282 - 1287
反应条件
in neat (no solvent) in a Pyrex tube, 0.5 h at 300°C; monitored by (11)B NMR and ESR;
参考文献
Inorganic Chemistry, , vol. 25, p. 2366 - 2372
反应条件
in neat (no solvent) inert atmosphere, room temperature; yield 100percent;
参考文献
Chemische Berichte, , vol. 128, # 7 p. 735 - 736
反应条件
in neat (no solvent) under N2, exclusion of air, reagents rapidly heated to 80°C; not sepd.; detected by NMR, IR;
参考文献
Chemische Berichte, , vol. 113, # 7 p. 2333 - 2341
反应条件
in neat (no solvent) under N2, with exclusion of moisture, reagents (1/1 mol ratio) gently warmed to room temp.; not sepd.; detected by NMR, IR;
参考文献
Chemische Berichte, , vol. 113, # 7 p. 2333 - 2341
