MoO3 is reacted with BCl3 to several products; MoCl6 is not produced;
参考文献
Brisdon, Alan K.; Graham, John T.; Hope, Eric G.; Jenkins, Delyth M.; Levason, William; Ogden, J. Steven
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , # 5 p. 1529 - 1532
MoO3 is reacted with SOCl2; MoCl6 is not produced;
参考文献
Brisdon, Alan K.; Graham, John T.; Hope, Eric G.; Jenkins, Delyth M.; Levason, William; Ogden, J. Steven
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1990 , # 5 p. 1529 - 1532
in acetonitrile MoO2Cl2 soln. in CH3CN was added to LiO(2,6-t-Bu2C6H3) soln. in CH3CN and mixt. was stirred for 1 h; solvent was removed in vacuo, solved in pentane, filtered and placed in-35°C freezer for 2 days; elem. anal.;
in acetonitrile MoO2Cl2 soln. in CH3CN was added to LiO(2,6-t-Bu2C6H3) soln. in CH3CN and mixt. was stirred for 1 h; solvent was removed in vacuo, solved in pentane, filtered and placed in-35°C freezer for 2 days; elem. anal.;
参考文献
Hanna, Tracy A.; Incarvito, Christopher D.; Rheingold, Arnold L.
Inorganic Chemistry, 2000 , vol. 39, # 4 p. 630 - 631
Castellanos, Nelson J.; Martinez, Fernando; Paez-Mozo, Edgar A.; Ziarelli, Fabio; Arzoumanian, Henri
Transition Metal Chemistry, 2012 , vol. 37, # 7 p. 629 - 637
