in neat (no solvent) vapour of MoO3 condensed and then reacted with excess of vapour of BCl3 at -196°C in vac.; heated to 20°C in vac., heated to 100°C;
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , p. 239 - 244
in gas thermal decomposition reaction in air between 0 and 1000°C, heating rate 10°C/min, between 150 and 220°C: PMe3, at 350°C MoO,Cl2 at 450°C MoOCl2 as intermediate, product from 950°C: MoO3;
in neat (no solvent) no further formation of MoOCl4;;
参考文献
Glukhov, I. A.; Shalukhina, L. M.; Zagranichnaya, V. Ya.
Dokl. Akad. Nauk Tadzh. SSR, 1968 , vol. 11, # 1 p. 34 - 36
C. A., 1968 , vol. 68, p. 118953
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Gmelin Handbook: Mo: SVol.B2, 1.6.5.6.2, page 33 - 35
