iodine in sulfuric acid complete oxidation of sulfuric H3PO2 with I2 at ambient temp. after 12-15 h; further oxidation of 1 percent formed H3PO3 forming H3PO4;;
参考文献
Archiv der Pharmazie (Weinheim, Germany), , vol. 240, p. 663 - 675
water; mercury dichloride in hydrogenchloride Kinetics; oxidation of a hydrochloric soln. of H3PO2 (0.005-0.1 mol/l) with HgCl2 (0.005-0.2 mol/l) at 25 °C;;
参考文献
Journal of the Chemical Society, , vol. 119, p. 1266 - 1277
sulfuric acid; nitric acid in sulfuric acid; nitric acid byproducts: nitrogen oxide; phosphorus dissolves even at 0 °C in a mixt. of HNO3:H2SO4 = 1:9 without evolution of gas; addn. of H2O to the soln. causes release of nitrous oxides and formation of H3PO4 and some H3PO3;; small amount of phosphorous acid;;
参考文献
Annalen der Physik (Weinheim, Germany), , vol. 70, p. 87 - 99
