hydrogen in neat (no solvent) reduction of gaseous PCl3 induced by a high voltage-Hg-arc; formation of dark red and yellow ppt. and a dark grey ppt. on the Hg electrodes;; formation of white crystals by fractionation;;
in neat (no solvent) dark electric discharge in a mixture of gaseous PCl3 and H2; formation of a scarlet-red pptn. and a colorless liquid with a yellow compound suspended in it;; filtration, distn. of the filtrate; crystn. of a white mass on cooling;;
参考文献
Besson, A.; Fournier, L.
C. r. Acad. Sci. (Paris), 1910 , vol. 150, p. 102 - 104
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Gmelin Handbook: P: MVol.C, 179, page 412 - 414
in neat (no solvent) Electric Arc; react. of Zn with PCl3 in an atmosphere of N2 under influence of a Zn arc; react. of Zn with PCl3 forming ZnCl2 and P and by-react. of Zn with PCl3 forming ZnCl2 and P2Cl4;;
参考文献
Gmelin Handbook: P: MVol.C, 185, page 427 - 429
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Stock, A.; Brandt, A.; Fischer, H.
Ber. dtsch. chem. Ges., 1925 , vol. 58, p. 643 - 657
in neat (no solvent) heating on light at 100 °C; formation of PCl3 and a orange-yellow or light red compound which is a mixt. of red P and P-chlorides;;
参考文献
Besson, A.; Fournier, L.
C. r. Acad. Sci. (Paris), 1910 , vol. 150, p. 102 - 104
Full Text Show Details
Gmelin Handbook: P: MVol.C, 179, page 412 - 414
water in water
decompn. with water under formation of HCl, H3PO3 and a solid compound;;
参考文献
Besson, A.; Fournier, L.
C. r. Acad. Sci. (Paris), 1910 , vol. 150, p. 102 - 104
Full Text Show Details
Gmelin Handbook: P: MVol.C, 179, page 412 - 414
