in neat (no solvent) in a sealed glass ampoule, 298 K, conversion was 48 percent, 64 and 90percent after 11, 38 or 133 h, resp., under dry N2; fractionation could not be performed succesfully;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 627, # 6 p. 1217 - 1224
in gas byproducts: H2S; equimolar amts. of F3SiH and S was reacted in an ampoule at 620 K for 48h; yield of F3SiSH was increased to 6 percent at 620 K during 10 h;; volatiles were trapped at 123 and 77 K, fractionated distn., products were identified by NMR and vapor phase IR;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 627, # 6 p. 1217 - 1224
in not given Kinetics; H produced by Hg-sensitized photolysis of H2;; monitored by Lyman-α absorption;;
参考文献
Arthur, Neville L.; Potzinger, Peter; Reimann, Bruno; Steenbergen, H. Peter
Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics, 1989 , vol. 85, p. 1447 - 1464
in gas byproducts: H2S; equimolar amts. of F3SiH and S was reacted in an ampoule at 620 K for 48h; yield of F3SiSH was increased to 6 percent at 620 K during 10 h;; volatiles were trapped at 123 and 77 K, fractionated distn., products were identified by NMR and vapor phase IR;
参考文献
Beckers, Helmut; Buerger, Hans
Zeitschrift fur Anorganische und Allgemeine Chemie, 2001 , vol. 627, # 6 p. 1217 - 1224
antimony(V) pentachloride in neat (no solvent)
byproducts: SiH4, HCl; at room temp. for 3 h; products distd. through two traps (-93°C, toluene slush, -130°C pentane slush), the second trap containing HSiF3 was isolated, evacuated for 30 min at -130°C (1.0 torr) to remove SiH4, HCl;
参考文献
Lin, S. T.; Groshens, T. J.; Klabunde, K. J.
Inorganic Chemistry, 1984 , vol. 23, p. 1 - 1
