caesium carbonate; bis(η3-allyl-μ-chloropalladium(II)) in 1,4-dioxane; water T=90°C; Suzuki-Miyaura cross-coupling reaction; 12 h;

2,2'-bis(di-p-tolyl-phosphino)-1,1'-binaphthyl; copper(I) oxide; 1,10-phenanthroline; palladium (II) bromide in 1-methyl-pyrrolidin-2-one T=50 - 190°C; Microwave irradiationInert atmosphere;

sodium t-butanolate; (N,N'-bis(2,6-di(i-Pr)phenyl)imidazol-2-ylidene)Pd(allyl)Cl in 1,4-dioxane T=60°C; Suzuki-Miyaura cross-coupling; 3 h;

potassium carbonate in anhydrous xylene T=90°C; Suzuki-Miyaura reaction; 3 h; Inert atmosphere;

N-heterocyclic carbene-based nickel(II) complex in tetrahydrofuran T=20°C; Kumada reaction; 12 h;

NiCl2[(4-MeOPh)3P]2; K3PO4*3H2O; tris(4-methoxyphenyl)-phosphine in toluene T=110°C; 5 h; Inert atmosphere;

tetrabutylammomium bromide; caesium carbonate; triphenylphosphine; palladium dichloride in N,N-dimethyl acetamide T=90°C; 1 h;

C21H18N8Ni2O(2+)*2F6P(1-) in tetrahydrofuran; 1-methyl-pyrrolidin-2-one T=20 - 80°C; Negishi coupling reaction;

1: 3-bromophenylacetic acid With resin-bound amine; benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate in N,N-dimethyl-formamide T=20°C; 18 h; 2: p-methylphenylboronic acid With tetrakis(triphenylphosphine) palladium(0); sodium carbonate in ethylene glycol dimethyl ether Suzuki coupling; 48 h; Heating; 3: With pyridine; trifluoroacetic anhydride in dichloromethane T=20°C; 16 h;

ethylene glycol dimethyl ether; Pd(1,3-bis(diphenylphosphino)-propane)Cl2 in tetrahydrofuran T=20°C; 1 h;