5,9-甲桥-6,7,8,9-四氢-7H-苯并环庚烯-7-酮合成路线 （共 14 条）
反应条件
2,6-di-tert-butyl-4-methyl-phenol; [Rh(nbd)(dppp)]PF6 in m-xylene T=135°C; 1.5 h;
参考文献
Murakami, Masahiro; Itahashi, Tamon; Ito, Yoshihiko
Journal of the American Chemical Society, 2002 , vol. 124, # 47 p. 13976 - 13977
反应条件
1.2: Zn 2.1: 81 percent / 2,6-di(tert-butyl-4-methylphenol) / [Rh(nbd)(dppp)]PF6 / m-xylene / 1.5 h / 135 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 124, # 47 p. 13976 - 13977
反应条件
formic acid Heating;
参考文献
Bulletin de la Societe Chimique de France, , p. 2617 - 2626
反应条件
1: tetrahydrofuran / 0.5 h 2: aq. HCO2H 3: aq. HCO2H / Heating View Scheme
参考文献
Journal of the American Chemical Society, , vol. 92, # 19 p. 5649 - 5657
反应条件
formic acid Heating;
参考文献
Journal of the American Chemical Society, , vol. 92, # 19 p. 5649 - 5657
反应条件
formic acid 18 h; Inert atmosphereReflux;
参考文献
Tetrahedron, , vol. 66, # 25 p. 4441 - 4451
反应条件
1: (i) iPrMgBr, Et2O, (ii) /BRN= 1361491/ 2: HCO2H / Heating View Scheme
参考文献
Bulletin de la Societe Chimique de France, , p. 2617 - 2626
反应条件
aluminum oxide; potassium tert-butylate 1.) THF, reflux, 6 h, 2.) petroleum ether, toluene; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 58, # 11 p. 3216 - 3218
反应条件
potassium tert-butylate in tetrahydrofuran 6 h; Heating2 equiv t-BuOK; Mechanism;
参考文献
Journal of Organic Chemistry, , vol. 58, # 11 p. 3216 - 3218
反应条件
potassium tert-butylate Mechanism;
参考文献
Journal of Organic Chemistry, , vol. 58, # 11 p. 3216 - 3218
