Hartwig, John F.; Muhoro, Clare N.; He, Xiaoming; Eisenstein, Odile; Bosque, Ramon; Maseras, Feliu
Journal of the American Chemical Society, 1996 , vol. 118, # 44 p. 10936 - 10937
pyridine; cyclohexanone in tetrahydrofuran; toluene byproducts: methylenecyclohexane; mixt. of soln. of Ti complex (1 equiv.) in THF/toluene and cyclohexanonewas heated at 80-85°C for 6 h under Ar; cooled to room temp.; py ridine and Me3SiCl were added; mixt. was heated at 80-85°C for 8 h; cooled; volatiles removed (vac.); triturated with THF and hexane;
参考文献
Berget, Patrick E.; Schore, Neil E.
Organometallics, 2006 , vol. 25, # 2 p. 552 - 553
hydrogenchloride in water; acetone byproducts: CH4; thermochemical measurements were carried out; confirmed by IR spectroscopic analysis;
参考文献
Calhorda, Maria J.; Dias, Alberto R.; Minas da Piedade, Manuel E.; Salema, Margarida S.; Simoes, Jose A. Martinho
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1: in toluene T=65°C; Schlenk techniqueInert atmosphere; 2: With N-bromosuccinmide in toluene T=-78°C; Schlenk techniqueInert atmosphere; 3: With water in toluene T=20°C; 1 h; Schlenk techniqueInert atmosphere; regioselective reaction;
