2-氯-1.3-丁二烯合成路线 (共 128 条)
反应条件
tBuFcMeSiH; triphenylmethylium tetrakis(pentafluorophenyl)borate in dichloromethane T=-30°C; Inert atmosphere; regioselective reaction;
参考文献
Klare, Hendrik F. T.; Bergander, Klaus; Oestreich, Martin
Angewandte Chemie - International Edition, 2009 , vol. 48, # 48 p. 9077 - 9079
反应条件
palladium dichloride T=110°C; 15 h;
参考文献
Hosaka,S.; Tsuji,J.
Tetrahedron, 1971 , vol. 27, p. 3821 - 3829
参考文献
Klebanskii et al.
Zhurnal Obshchei Khimii, 1947 , vol. 17, p. 235,243
Chem.Abstr., 1948 , p. 514
反应条件
sodium methylate; bis[2-(diphenylphosphino)phenyl] ether; tris(dibenzylideneacetone)dipalladium(0) chloroform complex in tetrahydrofuran 3 h; Heating;
参考文献
Ogasawara, Masamichi; Ikeda, Hisashi; Nagano, Takashi; Hayashi, Tamio
Organic Letters, 2001 , vol. 3, # 16 p. 2615 - 2617
反应条件
aluminium trichloride; hydroquinone
参考文献
Petrov,A.A. et al.
Zhurnal Organicheskoi Khimii, 1967 , vol. 3, # 4 p. 643 - 649,616 - 621
参考文献
Petrow et al.
Chimija chim.Technol.(NDVS)Chem.Abstr., 1959 , p. 123,124
Chimija chim.Technol.(NDVS)Chem.Abstr., 1959 , p. 16929
参考文献
Occidental Chemical Corporation
Patent: US5322954 A1, 1994 ;
反应条件
[1,3-bis(diphenylphosphino) propane] dichloronickel(II) in tetrahydrofuran T=0 - 20°C; Kumada-Tamao-Corriu coupling reaction; 26 h; Inert atmosphere;
参考文献
Payne, Alan D.; Bojase, Gomotsang; Paddon-Row, Michael N.; Sherburn, Michael S.
Angewandte Chemie, International Edition, 2009 , vol. 48, p. 4836 - 4839
Angewandte Chemie, 2009 , vol. 121, p. 4930 - 4933
反应条件
1: With magnesium; ethylene dibromide; zinc dibromide in tetrahydrofuran 2 h; Heating; 2: With copper(l) chloride in tetrahydrofuran T=-78°C; 1 h; 3: With lithium chloride; copper dichloride in tetrahydrofuran T=-78°C; 2 h;
参考文献
Payne, Alan D.; Willis, Anthony C.; Sherburn, Michael S.
Journal of the American Chemical Society, 2005 , vol. 127, # 35 p. 12188 - 12189
参考文献
Takenaka, Katsuhiko; Amamoto, Shuhei; Kishi, Hiroto; Takeshita, Hiroki; Miya, Masamitsu; Shiomi, Tomoo
Macromolecules, 2013 , vol. 46, # 18 p. 7282 - 7289