2,2-二甲基-1,3-丙二醇合成路线 （共 467 条）
反应条件
toluene-4-sulfonic acid in water; toluene T=80°C; 29 h; Inert atmosphereMolecular sieve;
参考文献
Liang, Yanliang; Peng, Bo; Liang, Jing; Tao, Zhanliang; Chen, Jun
Organic Letters, 2010 , vol. 12, # 6 p. 1204 - 1207
反应条件
toluene-4-sulfonic acid in toluene T=140°C; 24 h; Inert atmosphere;
参考文献
Robertson, Linsey; Hartley, Richard C.
Tetrahedron, 2009 , vol. 65, # 27 p. 5284 - 5292
反应条件
pyridine in water; benzene
参考文献
E. I. Du Pont de Nemours and Company
Patent: US4096341 A1, 1978 ;
反应条件
toluene; benzenesulfonic Acid
参考文献
Barnes; Fainman
Lubrication Eng., 1957 , vol. 13, p. 454,455
反应条件
1: With titanium(IV) isopropylate T=220°C; 8 h; 2: With sodium hydroxide in water Product distribution / selectivity;
参考文献
Kim, Hyunkyu; Lee, Kyeseok; Lee, Kyu Il; Chun, Byoungkue
Patent: US2007/15933 A1, 2007 ;
Location in patent: Page/Page column 6 ;
反应条件
4 A molecular sieve; toluene-4-sulfonic acid 1.) benzene, 6 h, reflux, 2.) benzene, 2 h, reflux; Yield given. Multistep reaction;
参考文献
Hu; Jayaraman; Oehlschlager
Journal of Organic Chemistry, 1999 , vol. 64, # 7 p. 2524 - 2526
反应条件
1: tri-isopropoxy-borane; 1-cyano-2-methoxybenzene With 2,2,6,6-tetramethylpiperidinyl-lithium in tetrahydrofuran; hexane T=-78 - 20°C; 2: 3-hydroxy-2,2-dimethylpropanol in tetrahydrofuran; hexane T=20°C; 1 h;
参考文献
Lysen, Morten; Hansen, Henriette M.; Begtrup, Mikael; Kristensen, Jesper L.
Journal of Organic Chemistry, 2006 , vol. 71, # 6 p. 2518 - 2520
反应条件
4 A molecular sieve in 1,4-dioxane 12 h; Heating;
参考文献
Maki, Toshikatsu; Ishihara, Kazuaki; Yamamoto, Hisashi
Organic Letters, 2005 , vol. 7, # 22 p. 5043 - 5046
Title/Abstract Full Text View citing articles Show Details
Maki, Toshikatsu; Ishihara, Kazuaki; Yamamoto, Hisashi
Tetrahedron, 2007 , vol. 63, # 35 p. 8645 - 8657
反应条件
magnesium sulfate in diethyl ether T=25°C; 20 h; Inert atmosphere;
参考文献
Matthew, Smitha C.; Glasspoole, Ben W.; Eisenberger, Patrick; Crudden, Cathleen M.
Journal of the American Chemical Society, 2014 , vol. 136, # 16 p. 5828 - 5831
反应条件
1: 3-hydroxy-2,2-dimethylpropanol With tetrakis(dimethylamino)diboron; potassium acetate in toluene T=80°C; 0.5 h; 2: 1-bromo-4-fluorobenzene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in toluene T=80°C; 22 h;
参考文献
BASF SE; SCHMIDT-LEITHOFF, Joachim; PICHLMAIR, Stefan; BELLO, Charles; BASF (CHINA) COMPANY LIMITED
Patent: WO2013/14579 A1, 2013 ;
Location in patent: Page/Page column 11; 12; 13 ;
