2,2-二甲基-1,3-丙二醇合成路线 （共 467 条）
反应条件
in chloroform-d1 T=20°C; 894 h; Title compound not separated from byproducts.;
参考文献
Roy, Chandra D.; Brown, Herbert C.
Monatshefte fur Chemie, 2007 , vol. 138, # 9 p. 879 - 887
反应条件
in chloroform-d1 T=20°C; 0.1 h; Title compound not separated from byproducts.;
参考文献
Roy, Chandra D.; Brown, Herbert C.
Monatshefte fur Chemie, 2007 , vol. 138, # 9 p. 879 - 887
反应条件
in chloroform-d1 T=20°C; 0.75 h; Title compound not separated from byproducts.;
参考文献
Roy, Chandra D.; Brown, Herbert C.
Monatshefte fur Chemie, 2007 , vol. 138, # 9 p. 879 - 887
反应条件
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
反应条件
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
参考文献
Bowie,R.A.; Musgrave,O.C.
Journal of the Chemical Society [Section] C: Organic, 1966 , p. 566 - 571
参考文献
Bowie,R.A.; Musgrave,O.C.
Journal of the Chemical Society, 1963 , p. 3945 - 3949
反应条件
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
反应条件
in dichloromethane all reactions under Ar atm.; soln. of BCl3 in CH2Cl2 added to stirred soln. of triarylstibane at 0°C, stirred for 2 h, allowed to warm toroom temp., solvent removed in vac., oil dissolved in MeOH, stirred for 30 min at room temp., diol added; stirred for 1 h, solvent removed in vac., chromy. (silica-gel, hexane/CH2Cl2);
参考文献
Yasuike, Shuji; Nakata, Kazuhide; Qin, Weiwei; Kaji, Toshiyuki; Kurita, Jyoji
Chemistry Letters, 2006 , vol. 35, # 12 p. 1402 - 1403
反应条件
1: 100 percent / toluene / 1 h / Heating 2: 98 percent / triphenylphosphine; diethylamine; CuI / PdCl2(PPh3)2 / dimethylformamide / 0.42 h / 120 °C / microwave irradiation View Scheme
参考文献
Zheng, Shi-Long; Reid, Suazette; Lin, Na; Wang, Binghe
Tetrahedron Letters, 2006 , vol. 47, # 14 p. 2331 - 2335
