in toluene; butan-1-ol Kinetics; byproducts: P(O)H(OC4H9), P(O)H(OH)(OC4H9), P(O)(OC4H9)3; Ar, a soln. of P4 (toluene) added to a soln. of peroxide and alcohol, heated to 25-50°C; not isolated, detected by gas chromy.;
参考文献
Journal of Molecular Catalysis A: Chemical, , vol. 267, # 1-2 p. 181 - 193
in neat (no solvent) byproducts: H4P2O6; addn. of air to a mixture of P4 vapor and H2O vapor; pptn. of P4OH as voluminous ppt. in the condensate by addn. of a large amount of air;; impured with H3PO2, H3PO3, H3PO4, H4P2O6; washing with water, acetone; extraction with CS2, washing with ether, drying in vacuum; content 89 weight-percent P, 0.8 weight-percent H;;
