air in neat (no solvent) passing 120 litre humid air over white P in 6 d at ambient temp., 1percent of the P are converted into H3PO2, 15-21percent into H3PO3, 72-77percent into H3PO4 and6-8percent into H4P2O6;;
[((C6H5)3P)2Pd(C4H8O)2](2+); HCl in tetrahydrofuran (N2); a soln. of P4 added dropwise to a soln. of Pd complex, stirred at 50°C for 1 h, deaerated H2O added, aq. HCl added; not isolated, detected by NMR;
参考文献
Russian Chemical Bulletin, , vol. 59, # 6 p. 1116 - 1118
