(1,5-环辛二烯)氯铑(I)二聚体合成路线 （共 52 条）
反应条件
in benzene-d6 dissolved in benzene under inert atm.; free phosphine is present in 12percent to total phosphorus content at 21°C, shift of the equil. upon addn. of 1 equiv of phosphine ligand or (RhCl(COD))2 confirmes the reversibility of the reaction; (31)P and (1)H NMR spectral data;
参考文献
Organometallics, , vol. 3, p. 657 - 663
反应条件
in benzene-d6 dissolution in benzene; free phosphine is present in 32percent to total phosphorus content at 21°C and ca. 45percent at 80°C, shift of the equil. upon addn. of 1 equiv of phosphine ligand or (RhCl(COD))2 confirmes the reversibility of the reaction; (31)P and (1)H NMR spectral data;
参考文献
Organometallics, , vol. 3, p. 657 - 663
反应条件
in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Organometallics, , vol. 7, p. 1957 - 1966
反应条件
in dichloromethane instant reaction; no sepn. of metal-contg. products (similar soly.);
参考文献
Organometallics, , vol. 7, p. 1957 - 1966
反应条件
in neat (no solvent) byproducts: C4H8OTe, H2O; (N2); heated the sample at a steady heating rate of 20°C/min to 248°C; DTG, TG;
参考文献
Thermochimica Acta, , vol. 162, p. 409 - 414
反应条件
in neat (no solvent) byproducts: C4H8Te, H2O; (N2); heated the sample at a steady heating rate of 20°C/min to 248°C; DTG, TG;
参考文献
Thermochimica Acta, , vol. 162, p. 409 - 414
反应条件
in toluene refluxing a mixt. of Rh-complex and Pt-compd. in toluene for 2 h (under N2, Schlenk technique);; pumping off, extn. (CH2Cl2), filtn. yields Pt-compd., evapn. of extract, chromy., elution (CH2Cl2/hexane) yields Rh-complex, elution (CH2Cl2), evapn., slow addn. of Et2O, cooling (-15°C), filtn., washing (Et2O), drying in vac., elem. anal.;;
参考文献
Inorganic Chemistry, , vol. 31, p. 969 - 974
反应条件
in methanol stirring (4 h, pptn.); filtration, washing (Et2O), drying (in air);
参考文献
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), , # 11 p. 2811 - 2820
反应条件
in benzene addn. of tmen to soln. of Rh-dimer in benzene; filtration; washed with benzene; air dried; elem. anal;
参考文献
Garralda, M. A.; Ibarlucea, L.
Journal of Organometallic Chemistry, 1986 , vol. 311, p. 225 - 232
反应条件
in dichloromethane under Ar; CH2Cl2 added to mixt. of Rh complex and Ph3CBF4, added acetonitrile; concd. in vac., pptd. by addn. of Et2O, filtered, washed with Et2O;
参考文献
Journal of the American Chemical Society, , vol. 105, # 25 p. 7288 - 7294
