in tetrahydrofuran Kinetics; mixing V-complex with anhyd. HCl in THF; solvent removal, extn. into hexane; filtration, evapn.; IR and NMR spectroscopy; elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 489, # 1-2 p. C22 - C25
in toluene molar ratio V-complex/Bu3SnNCS=1:2, evacuated sealed ampul (20°C, 120 h);
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, p. 577 - 580
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 37, p. 678 - 681
in toluene molar ratio V-complex/Bu3SnNCO=1:2, evacuated sealed ampul (20°C, 240 h);
参考文献
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), , vol. 37, p. 577 - 580
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, , vol. 37, p. 678 - 681
NaF in sulfur dioxide
AsF5 is condensed to a frozen soln. of Cp2VCl2 and NaF in SO2 at -196°C, warming up, stirring at room temp. for 12 h, removal of SO2 and AsF3 in vac.; residue is recrystd. from SO2; elem. anal.;
参考文献
Gowik, Petra; Klapoetke, Thomas M.; Siems, Karsten; Thewalt, Ulf
Journal of Organometallic Chemistry, 1992 , vol. 431, # 1 p. 47 - 53
Razuvaev, G. A.; Gordetsov, A. S.; Latyaeva, V. N.; Zimina, S. V.; Skobeleva, S. E.; et al.
Journal of Organometallic Chemistry, 1987 , vol. 329, p. 327 - 336
