1: With sodium hydroxide; potassium dihydrogenphosphate; air; phosphoric acid in water T=28°C; pH=8; 44 h; Microbiological reactionResolution of racemate; 2: With sulfuric acid in water optical yield given as percent ee;
参考文献
Hanson, Ronald L.; Davis, Brian L.; Chen, Yijun; Goldberg, Steven L.; Parker, William L.; Tully, Thomas P.; Montana, Michael A.; Patel, Ramesh N.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 9 p. 1367 - 1375
sodium hydroxide; potassium dihydrogenphosphate; air; phosphoric acid in water T=28°C; pH=8; 44 h; Microbiological reactionResolution of racemate; optical yield given as percent ee;
参考文献
Hanson, Ronald L.; Davis, Brian L.; Chen, Yijun; Goldberg, Steven L.; Parker, William L.; Tully, Thomas P.; Montana, Michael A.; Patel, Ramesh N.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 9 p. 1367 - 1375
1: With hydrogenchloride; sodium hydroxide; air; phosphoric acid in water T=28°C; pH=8; 46 h; aq. phosphate bufferMicrobiological reactionResolution of racemate; 2: With sulfuric acid in water optical yield given as percent ee;
参考文献
Hanson, Ronald L.; Davis, Brian L.; Chen, Yijun; Goldberg, Steven L.; Parker, William L.; Tully, Thomas P.; Montana, Michael A.; Patel, Ramesh N.
Advanced Synthesis and Catalysis, 2008 , vol. 350, # 9 p. 1367 - 1375
1: With ammonia; hydrogen; [RhCl(η2:η2-cycloocta-1,5-diene)]2; 2,2'-bis[[bis(3-sulfophenyl)phosphino]methyl]-4,4',7,7'-tetrasulfo-1,1'-binaphthyl octasodium salt in water T=60°C; P=24752.5 Torr; 16 h; 2: With hydrogenchloride in water Product distribution / selectivity;
参考文献
Degussa AG
Patent: US6884887 B1, 2005 ;
Location in patent: Page/Page column 14 ;