in solid solid-state synthesis from ScCl3 (4.6 mmol) and NaCH3COCHCOCH3 (18.0 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;
参考文献
Borisov, A. P.; Petrova, L. A.; Makhaev, V. D.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 10 - 12
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 15 - 17
in solid solid-state synthesis from NiCl2 (14.7 mmol) and NaCH3COCHCOCH3 (27.0 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;
参考文献
Borisov, A. P.; Petrova, L. A.; Makhaev, V. D.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 10 - 12
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 15 - 17
in solid solid-state synthesis from CuCl2 (14.1 mmol) and NaCH3COCHCOCH3 (28.7 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;
参考文献
Borisov, A. P.; Petrova, L. A.; Makhaev, V. D.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 10 - 12
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 15 - 17
in solid solid-state synthesis from VCl3 (9.5 mmol) and NaCH3COCHCOCH3 (28.7 mmol) by mechanical activation (vibrating quartz vessel for 2 h at 5 Hz); transferring product into dry box under inert atmosphere;; vac. sublimation (0.1 torr) at 150-200°C bath temp.;;
参考文献
Borisov, A. P.; Petrova, L. A.; Makhaev, V. D.
Journal of General Chemistry USSR (English Translation), 1992 , vol. 62, p. 10 - 12
Zhurnal Obshchei Khimii, 1992 , vol. 62, p. 15 - 17
in diethyl ether byproducts: pentafluorobenzene, NaCl; -50 - 20°C;
参考文献
Razuvaev, G. A.; Vyshinskaya, L.I.; Drobotenko, V. V.
Journal of General Chemistry USSR (English Translation), 1980 , vol. 50, p. 1241 - 1246
Zhurnal Obshchei Khimii, 1980 , vol. 50, p. 1535 - 1540
in toluene byproducts: NaCl; (N2); standard Schlenk technique; mixt. of Rh complex and Na(acac) in toluene was heated with stirring at 40°C for 3 h; filtered; tolune removed (vac.); extd. (hexane); filtered through pad ofCelite; hexane removed (vac.); elem. anal.;
参考文献
Burke, Jacquelyn M.; Benjamin Coapes; Goeta, Andres E.; Howard, Judith A.K.; Marder, Todd B.; Robins, Edward G.; Westcott, Stephen A.
Journal of Organometalic Chemistry, 2002 , vol. 649, # 2 p. 199 - 203
Abeywickrema, Ramyani; Bennett, Martin A.; Cavell, Kingsley J.; Kony, Michael; Masters, Anthony F.; Webb, Alison G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 1 p. 59 - 68
Abeywickrema, Ramyani; Bennett, Martin A.; Cavell, Kingsley J.; Kony, Michael; Masters, Anthony F.; Webb, Alison G.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1993 , # 1 p. 59 - 68
