Ti(OCH(CH3)2)4 in neat (no solvent)
under Ar, addn. of 1.5 equiv. of catecholborane to mixt. of 1.0 equiv. cyclohexene and 0.1 equiv. Ti(OCH(CH3)2)4, stirred for 12 h; not isolated, identified by (11)B-NMR spectroscopy;
参考文献
Burgess, Kevin; Donk, Wilfed A. van der
Organometallics, 1994 , vol. 13, p. 3616 - 3620
Ti(OCH(CH3)2)4 in tetrahydrofuran
under Ar, addn. of 1 mol ester to 0.1 mol of Ti(OCH(CH3)2)4, addn. of borane to mixt.; identified by (11)B-NMR spectroscopy, no trialkylborane found in the 11B-NMR spectrum after 12 h at 25°C;
参考文献
Burgess, Kevin; Donk, Wilfed A. van der
Organometallics, 1994 , vol. 13, p. 3616 - 3620
