3-氧代-1-环戊烯-1-羧酸甲酯合成路线 （共 12 条）
反应条件
tert.-butylhydroperoxide; Rh2(Cap)4; potassium carbonate in dichloromethane 1 h;
参考文献
Catino, Arthur J.; Forslund, Raymond E.; Doyle, Michael P.
Journal of the American Chemical Society, 2004 , vol. 126, # 42 p. 13622 - 13623
反应条件
potassium carbonate; 20percent Pd(OH)2/C in dichloromethane T=24°C; 48 h;
参考文献
Yu, Jin-Quan; Corey
Journal of the American Chemical Society, 2003 , vol. 125, # 11 p. 3232 - 3233
反应条件
chromium(VI) oxide; acetic anhydride; acetic acid in dichloromethane T=11 - 14°C;
参考文献
Lange, Gordon L.; Decicco, Carl P.; Willson, Jennifer; Strickland, Lou Anne
Journal of Organic Chemistry, 1989 , vol. 54, # 8 p. 1805 - 1810
反应条件
jones reagent in diethyl ether; acetone T=0°C; 0.5 h;
参考文献
Nantz, M. H.; Radisson, X.; Fuchs, P. L.
Synthetic Communications, 1987 , vol. 17, # 1 p. 55 - 70
反应条件
indium; ammonium chloride in ethanol; water T=90°C; 14 h;
参考文献
Ranu, Brindaban C.; Dutta, Jyotirmoy; Guchhait, Sankar K.
Organic Letters, 2001 , vol. 3, # 16 p. 2603 - 2605
反应条件
1: NaBH4, CeCl3 / methanol 2: mercuric chloride, samarium / tetrahydrofuran / 2 h / Ambient temperature 3: 58 percent / molecular sieve 5 Angstroem, PCC / CH2Cl2 / 24 h / Ambient temperature 4: 50 percent / triethylamine, lithium perchlorate / acetonitrile / 5 h / Irradiation View Scheme
参考文献
Cossy, Janine; Furet, Nathalie
Tetrahedron Letters, 1993 , vol. 34, # 50 p. 8107 - 8110
反应条件
(2S,5S)-5-benzyl-3-methyl-2-(5-methyl-furan-2-yl)-imidazolidin-4-one; trichloroacetic acid in diethyl ether T=-10°C; 1 h; Title compound not separated from byproducts.;
参考文献
Tuttle, Jamison B.; Ouellet, Stephane G.; MacMillan, David W. C.
Journal of the American Chemical Society, 2006 , vol. 128, # 39 p. 12662 - 12663
反应条件
glucose dehydrogenase; D-glucose; enoate-reductase YQJm from Bacillus subtilis mutant I69T; nicotinamide adenine dinucleotide phosphate T=30°C; pH=7; aq. phosphate bufferEnzymatic reaction; optical yield given as percent ee;
参考文献
Bougioukou, J. Despina; Kille, Sabrina; Taglieber, Andreas; Reetz, Manfredt.
Advanced Synthesis and Catalysis, 2009 , vol. 351, # 18 p. 3287 - 3305
反应条件
(2S,5S)-5-benzyl-3-methyl-2-(5-methyl-furan-2-yl)-imidazolidin-4-one; trichloroacetic acid in diethyl ether T=-10°C; 1 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 128, # 39 p. 12662 - 12663
反应条件
1: NaBH4, CeCl3 / methanol 2: mercuric chloride, samarium / tetrahydrofuran / 2 h / Ambient temperature 3: 58 percent / molecular sieve 5 Angstroem, PCC / CH2Cl2 / 24 h / Ambient temperature View Scheme
参考文献
Cossy, Janine; Furet, Nathalie; BouzBouz, Samir
Tetrahedron, 1995 , vol. 51, # 43 p. 11751 - 11764
