三甲基-[三(三甲基硅烷基)甲基]硅烷合成路线 （共 20 条）
反应条件
4,4'-di-tert-butylbiphenyl; lithium in tetrahydrofuran T=-90 - -80°C;
参考文献
Guijarro, Albert; Yus, Miguel
Tetrahedron, 1996 , vol. 52, # 5 p. 1797 - 1810
反应条件
1: (dichloromethyl)methylbis(trimethylsilyl)silane; methyllithium in diethyl ether T=20°C; 12 h; 2: chloro-trimethyl-silane T=20°C; 12 h;
参考文献
Schmohl, Kathleen; Reinke, Helmut; Oehme, Hartmut
European Journal of Inorganic Chemistry, 2001 , # 2 p. 481 - 489
反应条件
in tetrahydrofuran T=25°C;
参考文献
Mai, Khuong; Patil, Ghanshyam
Journal of Organic Chemistry, 1986 , vol. 51, # 18 p. 3545 - 3548
反应条件
in diethyl ether T=20°C; 0.5 h;
参考文献
Al-Juaid, Salih S.; Avent, Anthony G.; Eaborn, Colin; El-Hamruni, Salima M.; Hawkes, Simon A.; Hill, Michael S.; Hopman, Martijn; Hitchcock, Peter B.; Smith, J. David
Journal of Organometallic Chemistry, 2001 , vol. 631, # 1-2 p. 76 - 86
反应条件
lithium 1.) 750 deg C, 60 min, 2.) THF, -78 deg C; room temperature, 24 h; Multistep reaction. Title compound not separated from byproducts;
参考文献
Landro, Frederick J.; Gurak, John A.; Chinn, John W.; Newman, Robert M.; Lagow, Richard J.
Journal of the American Chemical Society, 1982 , vol. 104, # 25 p. 7345 - 7346
反应条件
1: 89 percent / Mg / -30 °C 2: 23 percent / diethyl ether / 0.5 h / 20 °C View Scheme
参考文献
Al-Juaid, Salih S.; Avent, Anthony G.; Eaborn, Colin; El-Hamruni, Salima M.; Hawkes, Simon A.; Hill, Michael S.; Hopman, Martijn; Hitchcock, Peter B.; Smith, J. David
Journal of Organometallic Chemistry, 2001 , vol. 631, # 1-2 p. 76 - 86
反应条件
1: Br2 / CCl4 / Heating 2: (i) Li, Et2O, (ii) /BRN= 1209232/, THF View Scheme
参考文献
Seyferth,D. et al.
Journal of Organometallic Chemistry, 1977 , vol. 142, p. 39 - 53
反应条件
1: BuLi / diethyl ether; hexane / -78 °C 2: 16 percent / diethyl ether / -78 to r.t. View Scheme
参考文献
Wiberg, Nils; Karampatses, Petros; Kim, Chung-Kyun
Chemische Berichte, 1987 , vol. 120, p. 1203 - 1212
反应条件
in diethyl ether T=-30°C; Yield given;
参考文献
Wiberg, Nils; Karampatses, Petros; Kim, Chung-Kyun
Chemische Berichte, 1987 , vol. 120, p. 1203 - 1212
反应条件
in various solvent(s) 725 h; electroreduction, anode: Al, cathode: stainless steel; Further byproducts given;
参考文献
Pons, P.; Biran, C.; Bordeau, M.; Dunogues, J.
Journal of Organometallic Chemistry, 1988 , vol. 358, p. 31 - 38
