hydrogen; lt;Rh(NBD)(PPh3)2gt;lt;ClO4gt; T=30°C; P=760 Torr; 8 h; catalytic hydrogenation of the title compound in the presence of various catalysts (cationic rhodium complexes); influence of the type of catalyst's ligand, reaction time and pressure on the activity of catalysts; Product distributionMechanism;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , p. 855 - 860
oxygen; dimethyl amine T=291°C; P=123 Torr; study of the oxidation of butane in the presence of primary and secondary amines; variation of pressure and time; mechanism for the formation of nitromethane is proposed; Product distribution;
参考文献
Bulletin de la Societe Chimique de France, , vol. 1, # 9-10 p. 337 - 342
