(R)-(-)-α-(三氟甲基)苄醇合成路线 （共 21 条）
反应条件
baker's yeast in water T=32°C; 4 h;
参考文献
Bucciarelli, Maria; Forni. Arrigo; Moretti, Irene; Torre, Giovanni
Synthesis, 1983 , # 11 p. 897 - 899
反应条件
anhydrous magnesium perchlorate; chiral bis(1,4-dihydronicotinamide) in chloroform; acetonitrile T=50°C; 11 h; influence of the chiral reagent; Product distribution;
参考文献
Journal of the American Chemical Society, , vol. 103, # 15 p. 4613 - 4615
反应条件
1: With C52H46I2O8; potassium phenolate in toluene T=-50°C; 1 h; Inert atmosphere; 2: With hydrogenchloride in tetrahydrofuran; water T=20°C; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Fluorine Chemistry, , vol. 130, # 8 p. 762 - 765
反应条件
chiral 2-(3',5'-di-t-butylPh)-2-phosphabicyclo[3.3.0]octane in n-heptane T=-20°C; 1 h; Title compound not separated from byproducts;
参考文献
Journal of the American Chemical Society, , vol. 125, # 14 p. 4166 - 4173
反应条件
vinyl acetate; lipase LIP in octane T=30°C; 0.4 h; Yields of byproduct given;
参考文献
Kato; Katayama; Gautam; Fujii; Kimoto
Bioscience, Biotechnology and Biochemistry, 1995 , vol. 59, # 2 p. 271 - 276
反应条件
hydrogen fluoride; water in acetonitrile T=20°C;
参考文献
Tetrahedron Asymmetry, , vol. 21, # 13-14 p. 1793 - 1796
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
hydrogen in toluene T=20°C; Orito reaction; P=750.075 Torr; optical yield given as percent eeenantioselective reaction;
参考文献
Catalysis Communications, , vol. 12, # 15 p. 1410 - 1414
反应条件
n-butyllithium in hexane; toluene T=0°C; 16 h;
参考文献
Tetrahedron Letters, , vol. 47, # 16 p. 2821 - 2824
反应条件
Birman's catalyst in di-isopropyl ether T=0°C; 2.5 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Tetrahedron, , vol. 65, # 11 p. 2232 - 2238
