1-(1-萘基)-2-(三甲基硅基)乙炔合成路线 （共 18 条）
反应条件
pyridine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; triphenylphosphine T=80°C; 12 h; Inert atmosphereSchlenk technique;
参考文献
Chang, Ning-Hui; Mori, Hiroki; Chen, Xi-Chao; Okuda, Yasuhiro; Okamoto, Takeru; Nishihara, Yasushi
Chemistry Letters, 2013 , vol. 42, # 10 p. 1257 - 1259
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in N,N-dimethyl-formamide T=50°C; 6 h; Inert atmosphere;
参考文献
Sugimoto, Kenji; Hayashi, Rie; Nemoto, Hideo; Toyooka, Naoki; Matsuya, Yuji
Organic Letters, 2012 , vol. 14, # 13 p. 3510 - 3513
反应条件
[{Ir(l-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine in toluene T=80°C; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Kownacki, Ireneusz; Orwat, Bartosz; Marciniec, Bogdan; Kownacka, Agnieszka
Tetrahedron Letters, 2014 , vol. 55, # 2 p. 548 - 550
反应条件
oxygen; lithium chloride; manganese (II) chloride in tetrahydrofuran T=-5 - 0°C; Inert atmosphere;
参考文献
Angewandte Chemie, International Edition, , vol. 48, # 36 p. 6731 - 6734
反应条件
bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine in tetrahydrofuran T=80°C; Sonogashira Cross-Coupling; 20 h; Inert atmosphere;
参考文献
Yamaji, Minoru; Maeda, Hajime; Minamida, Keita; Maeda, Tomohiro; Asai, Kengo; Konishi, Gen-Ichi; Mizuno, Kazuhiko
Research on Chemical Intermediates, 2013 , vol. 39, # 1 p. 321 - 345
反应条件
copper(l) iodide; diethylamine; bis-triphenylphosphine-palladium(II) chloride T=20°C; Sonogashira reaction; 5 h;
参考文献
Koumbis, Alexandros E.; Kyzas, Christos M.; Savva, Antri; Varvoglis, Anastasios
Molecules, 2005 , vol. 10, # 10 p. 1340 - 1350
反应条件
bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran 12 h; Heating;
参考文献
Gelman, Dmitri; Tsvelikhovsky, Dmitry; Molander, Gary A.; Blum, Jochanan
Journal of Organic Chemistry, 2002 , vol. 67, # 18 p. 6287 - 6290
反应条件
pyrrolidine; tetrabutylammomium bromide; [5-Cl-2-{(4-Cl-phenyl)-[(E)-HO-imino]methyl}phenyl-PdCl]2 in 1-methyl-pyrrolidin-2-one T=130°C; Sila-Sonogashira coupling; 22 h;
参考文献
Advanced Synthesis and Catalysis, , vol. 345, # 9-10 p. 1146 - 1158
反应条件
SPhos; C16H16Cl2N2O4Pd2; N-hexadecyl-N,N,N-trimethylammonium bromide; triethylamine in water T=130°C; Sonogashira Cross-Coupling; 0.5 h; Microwave irradiation;
参考文献
Advanced Synthesis and Catalysis, , vol. 355, # 1 p. 203 - 208
反应条件
triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) in tetrahydrofuran; diethyl ether; hexane T=75°C;
参考文献
John, Jens A.; Tour, James M.
Tetrahedron, 1997 , vol. 53, # 45 p. 15515 - 15534
