[(3-甲基丁-2-烯-1-基)硫代]苯合成路线 （共 66 条）
反应条件
1: Na, ethanol / Ambient temperature
2: hydrogen / <Ru3O(CH3COO)6(H2O)3>(1+)*CH3COO(1-) / dimethylformamide / 2 h / 80 °C / 3040 Torr / other catalyst: RuO2*nH2O
3: Na, ethanol / Ambient temperature
View Scheme
参考文献
Cere, Vanda; Massaccesi, Franco; Pollicino, Salvatore; Ricci, Alfredo
Synthetic Communications, 1996 , vol. 26, # 5 p. 899 - 907
反应条件
triphenylphosphine-3,3',3''-trisulfonic acid trisodium salt; palladium diacetate in hexane; water
T=20°C; 24 h;
参考文献
Komine, Nobuyuki; Sako, Akari; Hirahara, Shin-Ya; Hirano, Masafumi; Komiya, Sanshiro
Chemistry Letters, 2005 , vol. 34, # 2 p. 246 - 247
反应条件
1.1: NaH / tetrahydrofuran / 1 h / 0 °C
1.2: tetrahydrofuran / 1 h / 0 °C
2.1: 78 percent / Pd(PPh3)4 / tetrahydrofuran / 2 h / 25 °C
3.1: 75 percent / K2CO3; (Bu4N)I / Pd(OAc)2; PPh3 / dioxane / 4 h / 100 °C
View Scheme
参考文献
Harayama, Hiroto; Nagahama, Takayuki; Kozera, Toyohiro; Kimura, Masanari; Fugami, Keigo; Tanaka, Shuji; Tamaru, Yoshinao
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 2 p. 445 - 456
反应条件
ethanol; sodium
Substitution; 3.5 h; Heating;
参考文献
Bach, Thorsten; Koerber, Christina
Journal of Organic Chemistry, 2000 , vol. 65, # 8 p. 2358 - 2367
反应条件
1: 5 percent / hydrogen / RuO2*nH2O / methanol / 48 h / 60 °C / 6080 Torr
2: hydrogen / <Ru3O(CH3COO)6(H2O)3>(1+)*CH3COO(1-) / dimethylformamide / 2 h / 80 °C / 3040 Torr
3: Na, ethanol / Ambient temperature
View Scheme
参考文献
Cere, Vanda; Massaccesi, Franco; Pollicino, Salvatore; Ricci, Alfredo
Synthetic Communications, 1996 , vol. 26, # 5 p. 899 - 907
反应条件
copper(l) iodide in diethyl ether
T=-15°C; Inert atmosphere;
参考文献
Tomashevskii; Sokolov; Potekhin
Russian Journal of Organic Chemistry, 2010 , vol. 46, # 12 p. 1822 - 1825
反应条件
1: 78 percent / Pd(PPh3)4 / tetrahydrofuran / 2 h / 25 °C
2: 75 percent / K2CO3; (Bu4N)I / Pd(OAc)2; PPh3 / dioxane / 4 h / 100 °C
View Scheme
参考文献
Harayama, Hiroto; Nagahama, Takayuki; Kozera, Toyohiro; Kimura, Masanari; Fugami, Keigo; Tanaka, Shuji; Tamaru, Yoshinao
Bulletin of the Chemical Society of Japan, 1997 , vol. 70, # 2 p. 445 - 456
反应条件
1: hydrogen / <Ru3O(CH3COO)6(H2O)3>(1+)*CH3COO(1-) / dimethylformamide / 2 h / 80 °C / 3040 Torr
2: Na, ethanol / Ambient temperature
View Scheme
参考文献
Cere, Vanda; Massaccesi, Franco; Pollicino, Salvatore; Ricci, Alfredo
Synthetic Communications, 1996 , vol. 26, # 5 p. 899 - 907
反应条件
in methanol
T=50°C; 7 h; Heating;
参考文献
Deniau, Jean; Duong, Kiem N. V.; Gaudemer, Alain; Bougeard, Peter; Johnson, Michael D.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1981 , p. 393 - 398
反应条件
1: hydrogen / <Ru3O(CH3COO)6(H2O)3>(1+)*CH3COO(1-) / dimethylformamide / 2 h / 80 °C / 3040 Torr / other catalyst: RuO2*nH2O
2: Na, ethanol / Ambient temperature
View Scheme
参考文献
Cere, Vanda; Massaccesi, Franco; Pollicino, Salvatore; Ricci, Alfredo
Synthetic Communications, 1996 , vol. 26, # 5 p. 899 - 907
