tetra-butylammonium acetate; Pd EnCat-30TM in ethanol T=120°C; Suzuki cross-coupling; 0.166667 h; microwave irradiation;

1: 1-iodo-3-nitro-benzene With [PdCl2(1,3-bis(diphenylphosphino)propane)]; tBuCH2CH2B(H)NiPr2; triethylamine; potassium iodide in toluene T=110°C; Suzuki coupling; 1 h; Inert atmosphere; 2: ortho-iodochlorobenzene With caesium carbonate in ethanol; water; toluene T=90°C; Suzuki coupling; 15 h; Inert atmosphere;

sodium acetate Diazotization;