in neat (no solvent)
heating a mixt. of POCl3 and P2O5 (molar ratio 2:1 - 5:1) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3 and a small amount of condensated phosphoryl chlorides P(n)O(2n-1)Cl(2n+2);;
参考文献
Grunze, H.
Z. Anorg. Chem., 1958 , vol. 296, p. 63 - 72
Full Text Show Details
Gmelin Handbook: P: MVol.C, 205, page 469 - 471
in neat (no solvent)
heating a mixt. of POCl3 and P2O5 (molar ratio POCl3:P2O5 > 4) for 48 h; formation of a product containing POCl3, P2O3Cl4, P3O6Cl3; no formation of polyphosphoryl chlorides;;
参考文献
Grunze, H.
Z. Anorg. Chem., 1958 , vol. 296, p. 63 - 72
Full Text Show Details
Gmelin Handbook: P: MVol.C, 205, page 469 - 471
