in toluene (N2); SnCl4 (7.2 mmol) added to soln. of Fe complex (1.80 mmol) at 0 °C; soln. stirred for 12 h at room temp.; solvent pumped off; residue taken up in hexane; filtration; crystn. from hexane at -20 °C; elem. anal.;
参考文献
Burns, Gary T.; Colomer, Ernest; Corriu, Robert J. P.; Lheureux, Marc
Organometallics, 1987 , vol. 6, p. 1398 - 1406
in toluene (N2); SnCl4 added to soln. of Fe complex at 0 °C; soln. stirred for 12 h at room temp.; solvent pumped off; residue taken up in hexane; filtration; several crysts. at -20 °C; elem. anal.; from the mother liquors, after evapn., CH3SnCl3 obtained by sublimation and identified by its 1H NMR spectrum and its m.p.;
参考文献
Burns, Gary T.; Colomer, Ernest; Corriu, Robert J. P.; Lheureux, Marc
Organometallics, 1987 , vol. 6, p. 1398 - 1406
sodium chloride in water (CH3)2SnCl2 was added to a soln. of HgCl2 in aq. NaCl (artificial seawater), the flask was sealed from light, shaken for 30 d at room temp.; monitored by 199Hg NMR;
参考文献
Australian Journal of Chemistry, , vol. 39, p. 1167 - 1176
