1: With C76H56N2O2; Nb(OiPr)5 in chloroform; sodium chloride T=40°C; 0.5 h; 2: With dihydrogen peroxide in chloroform; water; sodium chloride T=40°C; 3: With sodium tetrahydroborate optical yield given as percent eeenantioselective reaction;
参考文献
Egami, Hiromichi; Oguma, Takuya; Katsuki, Tsutomu
Journal of the American Chemical Society, 2010 , vol. 132, # 16 p. 5886 - 5895
titanium(IV) isopropylate; tert.-butylhydroperoxide; (-)-(1S,3S)-1,2-bis(2-methoxyphenyl)ethane-1,2-diol in dichloromethane T=-20°C; 18 h;
参考文献
Yamamoto, Koji; Ando, Hiroyuki; Shuetake, Takashi; Chikamatsu, Hiroaki
Journal of the Chemical Society, Chemical Communications, 1989 , # 12 p. 754 - 756
lt;N-(1,8-naphthalenedicarbonyl)-tert-Leu-lt;N-bis(1-naphthyl); vanadium triisopropoxide oxide in toluene T=0°C; 80 h; Title compound not separated from byproducts.;
参考文献
Journal of the American Chemical Society, , vol. 122, # 42 p. 10452 - 10453
1: With Oxonereg;; ethylenediaminetetraacetic acid; chiral ketone C30H44O7; sodium hydrogencarbonate in acetonitrile T=0°C; pH=7 - 7.5; 12 h; 2: With tetrabutyl ammonium fluoride in tetrahydrofuran 3 h; Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 70, # 18 p. 7279 - 7289
