in tetrahydrofuran

lithium aluminium deuteride in tetrahydrofuran 7 h; Ambient temperatureother time, solvents; reaction of LiAlD4 and LiAlH4 with hindered alkyl iodides; single electron transfer pathway; effect of reaction conditions (concentrations, stoichiometry, solvents, light, reactor surfaces, etc.) on the nature of reaction; Product distribution;

lithium aluminium deuteride in tetrahydrofuran 48 h; variation of reaction vessels (effect of reactor surface); Product distribution;

THF-d8 (tetrahydrofuran-d8); lithium aluminium tetrahydride Ambient temperaturein a glove box and absence of light; different reagents; Product distributionMechanism;

lithium diisopropyl amide in tetrahydrofuran T=0°C; 48 h;

THF-d8 (tetrahydrofuran-d8); lithium aluminium tetrahydride Ambient temperaturein a glove box and absence of light; different reagents; Product distributionMechanism;