甲基 3-O-苄基-2-脱氧-2-(1,3-二氧代-1,3-二氢-2H-异吲哚-2-基)-6-O-(2,3,4-三-O-苄基-6-脱氧己糖吡喃糖苷)吡喃己糖苷合成路线 （共 7 条）
反应条件
molecular sieve; tetraethylammonium bromide in dichloromethane
6 h; Ambient temperature;
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
molecular sieve; tetraethylammonium bromide in dichloromethane
6 h; 2.4 equivalents of bromide reagent, rt, overnight;
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
1: 85 percent / p-toluenesulphonic acid / acetonitrile
2: 86 percent / sodium hydride / 1,2-dimethoxy-ethane
3: 88 percent / 60percent aqueous acetic acid / 0.5 h / 100 °C
4: 42 percent / tetraethylammonium bromide, molecular sieves / CH2Cl2 / 6 h / Ambient temperature
View Scheme
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
1: 86 percent / sodium hydride / 1,2-dimethoxy-ethane
2: 88 percent / 60percent aqueous acetic acid / 0.5 h / 100 °C
3: 42 percent / tetraethylammonium bromide, molecular sieves / CH2Cl2 / 6 h / Ambient temperature
View Scheme
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
1: 88 percent / 60percent aqueous acetic acid / 0.5 h / 100 °C
2: 42 percent / tetraethylammonium bromide, molecular sieves / CH2Cl2 / 6 h / Ambient temperature
View Scheme
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
1: 95 percent / silver zeolite / CH2Cl2 / 1 h / Ambient temperature
2: 85 percent / sodium methoxide / methanol
3: 85 percent / p-toluenesulphonic acid / acetonitrile
4: 86 percent / sodium hydride / 1,2-dimethoxy-ethane
5: 88 percent / 60percent aqueous acetic acid / 0.5 h / 100 °C
6: 42 percent / tetraethylammonium bromide, molecular sieves / CH2Cl2 / 6 h / Ambient temperature
View Scheme
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
反应条件
1: 85 percent / sodium methoxide / methanol
2: 85 percent / p-toluenesulphonic acid / acetonitrile
3: 86 percent / sodium hydride / 1,2-dimethoxy-ethane
4: 88 percent / 60percent aqueous acetic acid / 0.5 h / 100 °C
5: 42 percent / tetraethylammonium bromide, molecular sieves / CH2Cl2 / 6 h / Ambient temperature
View Scheme
参考文献
Schwartz; Lee; Carver; Krepinsky
Canadian Journal of Chemistry, 1985 , vol. 63, # 5 p. 1073 - 1079
